Abstract
Surfaces that display liquid contact angles greater than 150° along with low contact angle hysteresis for liquids with both high and low surface tension values are known as superomniphobic surfaces. Such surfaces are of interest for a diverse array of applications, including self-cleaning surfaces, nonfouling surfaces, stain-free clothing, spill-resistant protective wear, drag reduction, and fingerprint-resistant surfaces. Recently, significant advances have been made in understanding the criteria required to design superomniphobic surfaces. In this article, we discuss the roles of surface energy, roughness, re-entrant texture, and hierarchical structure in fabricating superomniphobic surfaces. We also provide a review of different superomniphobic surfaces reported recently in the literature and emphasize the need for mechanical, chemical, and radiation durability of superomniphobic surfaces for practical applications. Finally, we conclude with a discussion of the unresolved challenges in developing durable superomniphobic surfaces that define the scope for further improvements in the field.
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T.L. Sun, L. Feng, X.F. Gao, L. Jiang, Acc. Chem. Res. 38, 644 (2005).
J. Genzer, K. Efimenko, Biofouling 22, 339 (2006).
B.X. Leng, Z.Z. Shao, G. de With, W.H. Ming, Langmuir 25, 2456 (2009).
C. Lee, C.-J. Kim, Phys. Rev. Lett. 106 (2011).
X. Zhang, J. Zhao, Q. Zhu, N. Chen, M. Zhang, Q. Pan, ACS Appl. Mater. Interfaces 3, 2630 (2011).
H. Jin, M. Kettunen, A. Laiho, H. Pynnonen, J. Paltakari, A. Marmur, O. Ikkala, R.H.A. Ras, Langmuir 27, 1930 (2011).
M. Nosonovsky, B. Bhushan, Curr. Opin. Colloid Interface Sci. 14, 270 (2009).
X. Huang, X. Wen, J. Cheng, Z. Yang, Appl. Surf. Sci. 258, 8739 (2012).
R. Dufour, M. Harnois, Y. Coffinier, V. Thomy, R. Boukherroub, V. Senez, Langmuir 26, 17242 (2010).
Z.-G. Guo, W.-M. Liu, Appl. Phys. Lett. 90 (2007).
M.H. Jin, X.J. Feng, L. Feng, T.L. Sun, J. Zhai, T.J. Li, L. Jiang, Adv. Mater. 17, 1977 (2005).
J. Xi, L. Jiang, Ind. Eng. Chem. Res. 47, 6354 (2008).
B. Balu, V. Breedveld, D.W. Hess, Langmuir 24, 4785 (2008).
Y. Lai, C. Lin, J. Huang, H. Zhuang, L. Sun, T. Nguyen, Langmuir 24, 3867 (2008).
P. Kim, T.-S. Wong, J. Alvarenga, M.J. Kreder, W.E. Adorno-Martinez, J. Aizenberg, ACS Nano 6, 6569 (2012).
A. Lafuma, D. Quéré, Europhys. Lett. 96 (2011).
T.-S. Wong, S.H. Kang, S.K.Y. Tang, E.J. Smythe, B.D. Hatton, A. Grinthal, J. Aizenberg, Nature 477, 443 (2011).
D. Richard, D. Quéré, Europhys. Lett. 50, 769 (2000).
A. Tuteja, W. Choi, J.M. Mabry, G.H. McKinley, R.E. Cohen, Proc. Natl. Acad. Sci. U.S.A. 105, 18200 (2008).
A. Tuteja, W. Choi, M. Ma, J.M. Mabry, S.A. Mazzella, G.C. Rutledge, G.H. McKinley, R.E. Cohen, Science 318, 1618 (2007).
A. Tuteja, W. Choi, G.H. McKinley, R.E. Cohen, M.F. Rubner, MRS Bull. 33, 752 (2008).
S.S. Chhatre, W. Choi, A. Tuteja, K.C. Park, J.M. Mabry, G.H. McKinley, R.E. Cohen, Langmuir 26, 4027 (2010).
A.K. Kota, G. Kwon, W. Choi, J.M. Mabry, A. Tuteja, Nat. Commun. 3, 1025 (2012).
J. Yang, Z. Zhang, X. Xu, X. Zhu, X. Men, X. Zhou, J. Mater. Chem. 22, 2834 (2012).
S.P.R. Kobaku, A.K. Kota, D.H. Lee, J.M. Mabry, A. Tuteja, Angew. Chem. Int. Ed. 51, 10109 (2012).
K. Tsujii, T. Yamamoto, T. Onda, S. Shibuichi, Angew. Chem. Int. Ed. 36, 1011 (1997).
T. Young, Philos. Trans. R. Soc. London 95, 65 (1805).
R.E. Johnson, R.H. Dettre, in Contact Angle, Wettability and Adhesion, ACS Advances in Chemistry Series (American Chemical Society, Washington, DC, 1964), vol. 43.
R. Shuttleworth, G.L.J. Bailey, Discuss. Faraday Soc. 3, 16 (1948).
A. Marmur, Langmuir 19, 8343 (2003).
M. Nosonovsky, Langmuir 23, 3157 (2007).
N.A. Patankar, Langmuir 19, 1249 (2003).
R.N. Wenzel, Ind. Eng. Chem. 28, 988 (1936).
A.B.D. Cassie, S. Baxter, Trans. Faraday Soc. 40, 0546 (1944).
W. Chen, A.Y. Fadeev, M.C. Hsieh, D. Oner, J. Youngblood, T.J. McCarthy, Langmuir 15, 3395 (1999).
W. Choi, A. Tuteja, J.M. Mabry, R.E. Cohen, G.H. McKinley, J. Colloid Interface Sci. 339, 208 (2009).
A. Marmur, Langmuir 24, 7573 (2008).
A. Lafuma, D. Quéré, Nat. Mater. 2, 457 (2003).
M. Callies, D. Quéré, Soft Matter 1, 55 (2005).
S. Herminghaus, Europhys. Lett. 79 (2007).
W. Choi, A. Tuteja, S. Chhatre, J.M. Mabry, R.E. Cohen, G.H. McKinley, Adv. Mater. 21, 2190 (2009).
B. Bhushan, Y.C. Jung, in Nanotribology and Nanomechanics: Nanotribology, Biomimetics and Industrial Applications (Springer-Verlag, Berlin, 2011), vol. 2.
L.C. Gao, T.J. McCarthy, Langmuir 22, 2966 (2006).
Y. Su, B. Ji, Y. Huang, K.-C. Hwang, Langmuir 26, 18926 (2010).
A.K. Kota, Y. Li, J.M. Mabry, A. Tuteja, Adv. Mater. 24, 5838 (2012).
S. Pan, A.K. Kota, J.M. Mabry, A. Tuteja, J. Am. Chem. Soc. 135 (2), 578 (2012).
R.E. Johnson, R.H. Dettre, J. Phys. Chem. 68, 1744 (1964).
Y. Su, B. Ji, K. Zhang, H. Gao, Y. Huang, K. Hwang, Langmuir 26, 4984 (2010).
E. Bittoun, A. Marmur, Langmuir 28 (39), 13933 (2012).
L. Cao, T.P. Price, M. Weiss, D. Gao, Langmuir 24, 1640 (2008).
C.T. Hsieh, F.L. Wu, W.Y. Chen, J. Phys. Chem. C 113, 13683 (2009).
D. Wang, X. Wang, X. Liu, F. Zhou, J. Phys. Chem. C 114, 9938 (2010).
T. Fujii, Y. Aoki, H. Habazaki, Langmuir 27, 11752 (2011).
T. Darmanin, F. Guittard, S. Amigoni, E.T. de Givenchy, X. Noblin, R. Kofman, F. Celestini, Soft Matter 7, 1053 (2011).
J. Yang, Z. Zhang, X. Xu, X. Men, X. Zhu, X. Zhou, New J. Chem. 35, 2422 (2011).
J.P. Youngblood, N.R. Sottos, C. Extrand, MRS Bull. 33, 732 (2008).
J.P. Zhang, S. Seeger, Angew. Chem. Int. Ed. 50, 6652 (2011).
H. Wang, Y. Xue, J. Ding, L. Feng, X. Wang, T. Lin, Angew. Chem. Int. Ed. 50, 11433 (2011).
D. Bartolo, A. Boudaoud, G. Narcy, D. Bonn, Phys. Rev. Lett. 99 (2007).
V. Bertola, Int. J. Heat Mass Transf. 52, 1786 (2009).
X. Deng, L. Mammen, H.-J.R. Butt, D. Vollmer, Science 335, 67 (2012).
X. Wang, X. Liu, F. Zhou, W. Liu, Chem. Commun. 47, 2324 (2011).
Acknowledgements
We thank Charles Y.-C. Lee and the Air Force Office of Scientific Research (AFOSR) for financial support under grants FA9550–11–1-0017. We also thank the donors of the Office of Naval Research (ONR) for financial support under Grant N00014-12-1-0874.
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Kota, A.K., Choi, W. & Tuteja, A. Superomniphobic surfaces: Design and durability. MRS Bulletin 38, 383–390 (2013). https://doi.org/10.1557/mrs.2013.101
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DOI: https://doi.org/10.1557/mrs.2013.101