Skip to main content
Log in

Coherent light trapping in thin-film photovoltaics

  • Published:
MRS Bulletin Aims and scope Submit manuscript

Abstract

Thin-film photovoltaic technologies have an enormous potential to reduce the cost of solar electricity. However, because thin photoactive layers are used, optical absorption is incomplete unless light-trapping strategies are employed. Since conventional light-trapping approaches based on geometric scattering are less effective in thin-film cells, coherent light-trapping approaches that exploit the wave nature of light are being explored to enhance optical absorption. In this article, we look at the various strategies for coherent light trapping in thin-film solar cells, including photonic crystals, metal nanostructures, and multilayer stacks. The suitability of a particular strategy depends on factors such as configuration of the solar cell, process compatibility, cost, desired angular response, and materials usage. We also discuss the physical limits of light trapping in thin films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7

Similar content being viewed by others

References

  1. W. Shockley, H.J. Queisser, J. Appl. Phys. 32, 510 (1961).

    Google Scholar 

  2. E. Yablonovitch, J. Opt. Soc. Am. 72, 899 (1982).

    Google Scholar 

  3. T. Tiedje, E. Yablonovitch, G.D. Cody, B.G. Brooks, IEEE Trans. Electron Devices 31, 711 (1984).

    Google Scholar 

  4. E. Yablonovitch, G. Cody, IEEE Trans. Electron Devices 29, 300 (1982).

    Google Scholar 

  5. Zhao, M.A. Green, IEEE Trans. Electron. Devices 38, 1925 (1991).

    Google Scholar 

  6. R.R. Bilyalov, L. Stalmans, L. Schirone, C. Levy-Clement, IEEE Trans. Electron. Devices 46, 2035 (1999).

    Google Scholar 

  7. P. Campbell, M.A. Green, J. Appl. Phys. 62, 243 (1987).

    Google Scholar 

  8. J. Müller, B. Rech, J. Springer, M. Vanecek, Sol. Energy 77, 917 (2004).

    Google Scholar 

  9. J. Gee, in Twenty-Ninth IEEE Photovolt. Spec. Conf. (2002), pp. 150–153.

  10. M. Agrawal, Photonic Design for Efficient Solid-State Energy Conversion (Stanford University, Stanford, CA, 2008).

    Google Scholar 

  11. I. Tobías, A. Luque, A. Marti, J. Appl. Phys. 104, 034502 (2008).

    Google Scholar 

  12. P.N. Saeta, V.E. Ferry, D. Pacifici, J.N. Munday, H.A. Atwater, Opt. Express 17, 20975 (2009).

    Google Scholar 

  13. Z. Yu, A. Raman, S. Fan, in Optics for Solar Energy, OSA Technical Digest (CD) (Optical Society of America, 2010), paper PDSWB1.

  14. M.A. Green, Progr. Photovoltaics (2011), in press.

  15. Z. Yu, A. Raman, S. Fan, PNAS 107, 17491 (2010).

    Google Scholar 

  16. J. Joannopoulos, R. Meade, J. Winn, Photonic Crystals: Molding the Flow of Light (Princeton, Princeton, NJ, 1995).

    Google Scholar 

  17. Y. Fink, J.N. Winn, S. Fan, C. Chen, J. Michel, J.D. Joannopoulos, E.L. Thomas, Science 282, 1679 (1998).

    Google Scholar 

  18. L. Zeng, Y. Yi, C.-Y. Hong, X. Duan, L.C. Kimerling, in Mater. Res. Soc. Symp. Proc. (Materials Research Society, Boston, MA, 2005), vol. 862.

  19. L. Zeng, P. Bermel, Y. Yi, N. Feng, C.-Y. Hong, X. Duan, J.D. Joannopoulos, L.C. Kimerling, in Mater. Res. Soc. Symp. Proc. (Materials Research Society, Boston, MA, 2006), vol. 974E.

  20. L. Zeng, Y. Yi, C.-Y. Hong, J. Liu, N. Ning Feng, X. Duan, L.C. Kimerling, B. Alamariu, Appl. Phys. Lett. 89, 111 (2006).

    Google Scholar 

  21. N. Feng, J. Michel, L. Zeng, J. Liu, C.-Y. Hong, L.C. Kimerling, X. Duan, IEEE Trans. Electron Devices 54, 1926 (2007).

    Google Scholar 

  22. P. Bermel, C. Luo, L. Zeng, L.C. Kimerling, J.D. Joannopoulos, Opt. Express 15, 16986 (2007).

    Google Scholar 

  23. P. O’Brien, N.P. Kherani, A. Chutinan, G.A. Ozin, S. John, S. Zukotynski, Adv. Mater. 20, 1577 (2008).

    Google Scholar 

  24. P. O’Brien, N.P. Kherani, A. Chutinan, G.A. Ozin, S. John, S. Zukotynski, in 34th IEEE Photovoltaic Specialists Conference (PVSC) (2009).

  25. A. Mihi, H. Miguez, J. Phys. Chem. B 109 (15), 968 (2005).

    Google Scholar 

  26. A. Mihi, F.J. López-Alcaraz, H. Miguez, Appl. Phys. Lett. 88, 193110 (2006).

    Google Scholar 

  27. S. Colodrero, A. Mihi, L. Häggman, M. Ocaña, G. Boschloo, A. Hagfeldt, H. Miguez, Adv. Mater. 21, 764 (2009).

    Google Scholar 

  28. G. Lozano, S. Colodrero, O. Caulier, M.E. Calvo, H. Miguez, J. Phys. Chem. C 114, 3681 (2010).

    Google Scholar 

  29. J.Y. Lee, S. Lee, J. Park, Y. Jun, Y. Lee, K. Kim, J.H. Yun, K.Y. Cho, Opt. Express 18, A522 (2010).

  30. J.G. Mutitu, S. Shi, C. Chen, T. Creazzo, A. Barnett, C. Honsberg, D.W. Prather, Opt. Express 16, 15238 (2008).

    Google Scholar 

  31. D. Zhou, R. Biswas, J. Appl. Phys. 103 (9), 093102 (2008).

  32. L. Zeng, P. Bermel, Y. Yi, B.A. Alamariu, K.A. Broderick, J. Liu, C. Hong, X. Duan, J. Joannopoulos, L.C. Kimerling, Appl. Phys. Lett. 93, 221105 (2008).

    Google Scholar 

  33. R. Biswas, J. Bhattacharya, B. Lewis, N. Chakravarty, V. Dalal, Sol. Energy Mater. Sol. Cells 94, 2337 (2010).

    Google Scholar 

  34. B. Curtin, R. Biswas, V. Dalal, Appl. Phys. Lett. 95, 231102 (2009).

    Google Scholar 

  35. J. Gjessing, E.S. Marstein, A. Sudbø, Opt. Express 18, 5481 (2010).

    Google Scholar 

  36. A. Bielawny, J. Üpping, P.T. Miclea, R.B. Wehrspohn, C. Rockstuhl, F. Lederer, M. Peters, L. Steidl, R. Zentel, S.-M. Lee, M. Knez, A. Lambertz, R. Carius, Phys. Status Solidi A 205, 2796 (2008).

    Google Scholar 

  37. A. Bielawny, C. Rockstuhl, F. Lederer, R.B. Wehrspohn, Opt. Express 17, 8439 (2009).

    Google Scholar 

  38. P.G. O’Brien, A. Chutinan, K. Leong, N.P. Kherani, G.A. Ozin, S. Zulotynski, Opt. Express 18, 4478 (2010).

    Google Scholar 

  39. L. Stolz Roman, O. Inganäs, T. Granlund, T. Nyberg, M. Svensson, M.R. Andersson, J.C. Hummelen, Adv. Mater. 12, 189 (2000).

    Google Scholar 

  40. Y.C. Lee, C.F. Huang, J.Y. Chang, M.L. Wu, Opt. Express 16, 7969 (2008).

    Google Scholar 

  41. A. Chutinan, N.P. Kherani, S. Zukotynski, Opt. Express 17, 8871 (2009).

    Google Scholar 

  42. S. Zanotto, M. Liscidini, L.C. Andreani, Opt. Express 18, 4260 (2010).

    Google Scholar 

  43. Y. Park, E. Drouard, O.E. Daif, X. Letartre, P. Viktorovitch, A. Fave, A. Kaminski, M. Lemiti, C. Seassal, Opt. Express 17, 14312 (2009).

    Google Scholar 

  44. O.E. Daif, E. Drouard, G. Gomard, A. Kaminski, A. Fave, M. Lemiti, S. Ahn, S. Kim, P. Cabarrocas, H. Jeon, C. Seassal, Opt. Express 18, A293 (2010).

  45. I. Prieto, B. Galiana, P.A. Postigo, C. Algora, L.J. Martinez, I. Rey-Stolle, Appl. Phys. Lett. 94, 191102 (2009).

    Google Scholar 

  46. S. Basu Mallick, M. Agrawal, P. Peumans, Opt. Express 18, 5691 (2010).

    Google Scholar 

  47. B.M. Kayes, H.A. Atwater, N.S. Lewis, J. Appl. Phys. 97, 114302 (2005).

    Google Scholar 

  48. L. Tsakalakos, J. Balch, J. Fronheiser, B.A. Korevaar, O. Sulima, J. Rand, Appl. Phys. Lett. 91, 233117 (2007).

    Google Scholar 

  49. T. Stelzner, M. Pietsch, G. Andrä, F. Falk, E. Ose, S. Christiansen, Nanotechnology 19, 295203 (2008).

    Google Scholar 

  50. O. Gunawan, S. Guha, Sol. Energy Mater. Sol. Cells 93, 1388 (2009).

    Google Scholar 

  51. V. Sivakov, G. Andrä, A. Gawlik, A. Berger, J. Plentz, F. Falk, S.H. Christiansen, Nano Lett. 9, 1549 (2009).

    Google Scholar 

  52. L. Hu, G. Chen, Nano Lett. 7, 3249 (2007).

    Google Scholar 

  53. O. Muskens, J.G. Rivas, R.E. Algra, E.P. Bakkers, A. Lagendijk, Nano Lett. 8, 2638 (2008).

    Google Scholar 

  54. J. Zhu, C.-M. Hsu, Z. Yu, S. Fan, Y. Cui, Nano Lett. 9, 279 (2009).

    Google Scholar 

  55. C. Lin, M.L. Povinelli, Opt. Express 17, 19371 (2009).

    Google Scholar 

  56. L. Cao, P. Fan, A.P. Vasudev, J.S. White, Z. Yu, W. Cai, J.A. Schuller, S. Fan, M.L. Brongersma, Nano Lett. 10, 439 (2010).

    Google Scholar 

  57. B. Tian, X. Zheng, T.J. Kempa, Y. Fang, N. Yu, G. Yu, J. Huang, C.M. Lieber, Nature 449, 885 (2007).

    Google Scholar 

  58. T.J. Kempa, B. Tian, D.R. Kim, J. Hu, X. Zheng, C.M. Lieber, Nano Lett. 8, 3456 (2008).

    Google Scholar 

  59. M.D. Kelzenberg, D.B. Turner-Evans, B.M. Kayes, M.A. Filler, M.C. Putnam, N.S. Lewis, H.A. Atwater, Nano Lett. 8, 710 (2008).

    Google Scholar 

  60. M.D. Kelzenberg, S.W. Boettcher, J.A. Petykiewicz, D.B. Turner-Evans, M.C. Putnam, E.L. Warren, J.M. Spurgeon, R.M. Briggs, N.S. Lewis, H.A. Atwater, Nat. Mater. 9, 239 (2010).

    Google Scholar 

  61. E. Garnett, P. Yang, Nano Lett. 10, 1082 (2010).

    Google Scholar 

  62. S.E. Han, G. Chen, Nano Lett. 10, 1012 (2010).

    Google Scholar 

  63. D. Duche, L. Escoubas, J.-J. Simon, P. Torchio, W. Vervisch, F. Flory, Appl. Phys. Lett. 92, 193310 (2008).

    Google Scholar 

  64. J.R. Tumbleston, D.H. Ko, E.T. Samulski, R. Lopez, Appl. Phys. Lett. 94, 043305 (2009).

    Google Scholar 

  65. J.R. Tumbleston, D.-H. Ko, R. Lopez, E.T. Samulski, in Proc. SPIE 7047, 70470S-1-9 (2008).

  66. D.-H. Ko, J.R. Tumbleston, L. Zhang, S. Williams, J.M. Desimone, R. Lopez, E.T. Samulski, Nano Lett. 9, 2742 (2009).

    Google Scholar 

  67. J.R. Tumbleston, D.H. Ko, E.T. Samulski, R. Lopez, Opt. Express 17, 7670 (2009).

    Google Scholar 

  68. H.A. Atwater, A. Polman, Nat. Mater. 9, 205 (2010).

    Google Scholar 

  69. V.E. Ferry, J. Munday, H.A. Atwater, Adv. Mater. 22, 4794 (2010).

    Google Scholar 

  70. V.E. Ferry, L.A. Sweatlock, D. Pacifici, H.A. Atwater, Nano Lett. 8, 4391 (2008).

    Google Scholar 

  71. H.R. Stuart, D.G. Hall, Appl. Phys. Lett. 69, 2327 (1996).

    Google Scholar 

  72. H.R. Stuart, D.G. Hall, Appl. Phys. Lett. 73, 3815 (1998).

    Google Scholar 

  73. K.R. Catchpole, A. Polman, Appl. Phys. Lett. 93, 191113 (2008).

    Google Scholar 

  74. K.R. Catchpole, A. Polman, Opt. Express 16, 21793 (2008).

    Google Scholar 

  75. Y. Akimov, W. Koh, Plasmonics 5 (2010).

  76. F.J. Tsai, J.Y. Wang, J.J. Huang, Y.W. Kiang, C.C. Yang, Opt. Express 18, A207 (2010).

  77. F.J. Beck, A. Polman, K.R. Catchpole, J. Appl. Phys. 105, 114310 (2009).

    Google Scholar 

  78. F.J. Beck, S. Mokkapati, A. Polman, K.R. Catchpole, Appl. Phys. Lett. 96, 033113 (2010).

    Google Scholar 

  79. R.A. Pala, J. White, E. Barnard, J. Liu, M.L. Brongersma, Adv. Mater. 21, 3504 (2009).

    Google Scholar 

  80. S. Pillai, K.R. Catchpole, T. Trupke, M.A. Green, J. Appl. Phys. 101, 093105 (2007).

    Google Scholar 

  81. D.M. Schaadt, B. Feng, E.T. Yu, Appl. Phys. Lett. 86, 063106 (2005).

    Google Scholar 

  82. D. Derkacs, S.H. Lim, P. Matheu, W. Mar, E.T. Yu, Appl. Phys. Lett. 89, 093103 (2006).

    Google Scholar 

  83. P. Matheu, S.H. Lim, D. Derkacs, C. McPheeters, E.T. Yu, Appl. Phys. Lett. 93, 113108 (2008).

    Google Scholar 

  84. D. Derkacs, W.V. Chen, P.M. Matheu, S.H. Lim, P.K.L. Yu, E.T. Yu, Appl. Phys. Lett. 93, 091107 (2008).

    Google Scholar 

  85. S. Fahr, C. Rockstuhl, F. Lederer, Appl. Phys. Lett. 95, 121105 (2009).

    Google Scholar 

  86. A.P. Kulkarni, K.M. Noone, K. Munechika, S.R. Guyer, D.S. Ginger, Nano Lett. 10, 1501 (2010).

    Google Scholar 

  87. C. Rockstuhl, S. Fahr, F. Lederer, J. Appl. Phys. 104, 123102 (2008).

    Google Scholar 

  88. V.E. Ferry, M.A. Verschuuren, H.B.T. Li, R.E.I. Schropp, H.A. Atwater, A. Polman, Appl. Phys. Lett. 95, 183503 (2009).

    Google Scholar 

  89. K.R. Catchpole, A. Polman, Opt. Express 16, 21793 (2008).

    Google Scholar 

  90. J.K. Mapel, M. Singh, M.A. Baldo, K. Celebi, Appl. Phys. Lett. 90, 121102 (2007).

    Google Scholar 

  91. K. Tvingstedt, N.-K. Persson, O. Inganas, A. Rahachou, I. Zozoulenko, Appl. Phys. Lett. 91, 113511 (2007).

    Google Scholar 

  92. T.D. Heidel, J.K. Mapel, M. Singh, K. Celebi, M.A. Baldo, Appl. Phys. Lett. 91, 093506 (2007).

    Google Scholar 

  93. M.-G. Kang, T. Xu, H.J. Park, X. Luo, L.J. Guo, Adv. Funct. Mater. 1 (2010).

  94. M. Kirkengena, J. Bergli, Y.M. Galperin, J. Appl. Phys. 102, 093713 (2007).

    Google Scholar 

  95. C. Hägglund, M. Zäch, G. Petersson, B. Kasemo, Appl. Phys. Lett. 92, 053110 (2008).

    Google Scholar 

  96. C. Hägglund, S. Appel, B. Kasemo, Nano. Lett. 10, 3135 (2010).

    Google Scholar 

  97. K. Nakayama, K. Tanabe, H.A. Atwater, Appl. Phys. Lett. 93, 121904 (2008).

    Google Scholar 

  98. T. Kume, S. Hayashi, H. Ohkuma, K. Yamamoto, Jpn. J. Appl. Phys. 34, 6448 (1995).

    Google Scholar 

  99. M. Westphalen, U. Kreibig, J. Rostalski, H. Lüth, D. Meissner, Sol. Energy Mater. Sol. Cells 61, 97 (2000).

    Google Scholar 

  100. C. Hägglund, M. Zäch, B. Kasemo, Appl. Phys. Lett. 92, 013113 (2008).

    Google Scholar 

  101. R.B. Konda, R. Mundle, H. Mustafa, O. Bamiduro, A.K. Pradhan, U.N. Roy Y. Cui, A. Burger, Appl. Phys. Lett. 91, 191111 (2007).

    Google Scholar 

  102. J.Y. Wang, F.J. Tsai, J.J. Huang, C.Y. Chen, N. Li, Y.W. Kiang, C.C. Yang, Opt. Express 18, 2682 (2010).

    Google Scholar 

  103. P. Peumans, V. Bulovic, S.R. Forrest, Appl. Phys. Lett. 76, 2650 (2000).

    Google Scholar 

  104. S.-S. Kim, S.-I. Na, J. Jo, D.-Y. Kim, Y.-C. Nah, Appl. Phys. Lett. 93, 073307 (2008).

    Google Scholar 

  105. A.J. Morfa, K.L. Rowlen, T.H. Reilly, M.J. Romero, J. Van de Lagemaat, Appl. Phys. Lett. 92, 013504 (2008).

    Google Scholar 

  106. N.C. Lindquist, W.A. Luhman, S.-H. Oh, R.K. Holmes, Appl. Phys. Lett. 93, 123308 (2008).

    Google Scholar 

  107. H. Shen, P. Bienstman, B. Maes, J. Appl. Phys. 106, 073109 (2009).

    Google Scholar 

  108. F.-C. Chen, J.-L. Wu, C.-L. Lee, Y. Hong, C.-H. Kuo, M.H. Huang, Appl. Phys. Lett. 95, 013305 (2009).

    Google Scholar 

  109. B.P. Rand, P. Peumans, S.R. Forrest, J. Appl. Phys. 96, 7519 (2004).

    Google Scholar 

  110. S. Fujimori, R. Dinyari, J.-Y. Lee, P. Peumans, Nano Lett. (2009).

  111. J.-Y. Lee, P. Peumans, Opt. Express 18, 10078 (2010).

    Google Scholar 

  112. M. Niggemann, M. Riede, A. Gombert, K. Leo, Phys. Status Solidi A 205, 2862 (2008).

    Google Scholar 

  113. P. Peumans, V. Bulovic, S.R. Forrest, Appl. Phys. Lett. 76, 2650 (2000).

    Google Scholar 

  114. B.P. Rand, J. Li, J. Xue, R.J. Holmes, M.E. Thompson, S.R. Forrest, Adv. Mater 17, 2714 (2005).

    Google Scholar 

  115. M. Hiramoto, H. Fujiwara, M. Yokoyama, J. Appl. Phys. 72, 3781 (1992).

    Google Scholar 

  116. M. Hiramoto, K. Ihara, H. Fukusumi, M. Yokoyama, J. Appl. Phys. 78, 7153 (1995).

    Google Scholar 

  117. M. Pfeiffer, A. Beyer, B. Plonnigs, A. Nollau, T. Fritz, K. Leo, D. Schlettwein, S. Hiller, D. Wohrle, Sol. Energy Mater. Sol. Cells 63, 83 (2000).

    Google Scholar 

  118. J. Drechsel, B. Mannig, F. Kozlowski, M. Pfeiffer, K. Leo, H. Hoppe, Appl. Phys. Lett. 86, 244102 (2005).

    Google Scholar 

  119. K. Walzer, B. Maennig, M. Pfeiffer, K. Leo, Chem. Rev. 107, 1233 (2007).

    Google Scholar 

  120. J. Gilot, I. Barbu, M.W. Wienk, R.A. Janssen, Appl. Phys. Lett. 91, 113520 (2007).

    Google Scholar 

  121. J.Y. Kim, S.H. Kim, H.-H. Lee, K. Lee, W. Ma, X. Gong, A.J. Heeger, Adv. Mater. 18, 572 (2006).

    Google Scholar 

  122. A. Roy, S.H. Park, S. Cowan, M.H. Tong, S. Cho, K. Lee, A.J. Heeger, Appl. Phys. Lett. 95, 013302 (2009).

    Google Scholar 

  123. B. O’Connor, K.H. An, K.P. Pipe, Y. Zhao, M. Shtein, Appl. Phys. Lett. 89, 233502 (2006).

    Google Scholar 

  124. V. Andersson, D.M. Huang, A.J. Moule, O. Inganas, Appl. Phys. Lett. 94, 043302 (2009).

    Google Scholar 

  125. K. Kishino, M.S. Unlu, J.-I. Chyi, J. Reed, L. Arsenault, H. Morkoc, IEEE J. Quantum Electron. 27, 2025 (1991).

    Google Scholar 

  126. M. Agrawal, P. Peumans, Opt. Express 16, 5385 (2008).

    Google Scholar 

Download references

Acknowledgments

Shrestha Basu Mallick and Nicholas P. Sergeant are joint first authors of this article.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shrestha Basu Mallick.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mallick, S.B., Sergeant, N.P., Agrawal, M. et al. Coherent light trapping in thin-film photovoltaics. MRS Bulletin 36, 453–460 (2011). https://doi.org/10.1557/mrs.2011.113

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/mrs.2011.113

Navigation