Abstract
Field emission (FE) measurements are reported from carbon nanotube (CNT) fibers and laser-patterned free standing films fabricated by direct online condensation from a floating catalyst chemical vapor deposition reactor. Fiber and film cathodes showed stable emission in the 1–2 mA current (I) range at maximum cathode temperatures less than 1000 °C; film cathodes show localized heating at the triangular tips and higher maximum temperatures than the fibers. Fowler-Nordheim (FN) analysis indicated a change in the morphology of the emitters with increasing external electrical field (Eext). Fiber cathode I-Eext data are interpreted as FN emission from the fiber tip which is eventually limited by space-charge effects. At higher Eext, FN emission from the fiber sidewall occurs. The single fiber cathode stopped emitting abruptly when field induced self-heating effects became significant. For CNT films, self-heating effects can destroy a portion of the film, but FE can still occur from other areas.
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ACKNOWLEDGMENTS
This work was supported by Air Force contract FA8650-11-D-5401 at the Materials & Manufacturing Directorate (AFRL/RXAP) The authors thank John Luginsland at AFOSR and Scott Dudley and Victor Putz of EOARD for their support.
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Fairchild, S.B., Bulmer, J.S., Sparkes, M. et al. Field emission from laser cut CNT fibers and films. Journal of Materials Research 29, 392–402 (2014). https://doi.org/10.1557/jmr.2013.322
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DOI: https://doi.org/10.1557/jmr.2013.322