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Studies of the growth parameters for silver nanoparticle synthesis by inert gas condensation

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Abstract

Silver nanoparticles were synthesized by an inert gas condensation method using flowing helium in the process chamber. Nucleation, growth mechanism, and the kinetics of nanoparticle formation in vapor phase are studied. Effect of process parameters, such as evaporation temperature and inert gas pressure, on the particle crystallinity, morphology, and size distribution are examined. Particles were synthesized at evaporation temperatures of 1123, 1273, and 1423 K and at helium pressures of 0.5, 1, 5, 50, and 100 Torr. Synthesized silver nanoparticles were characterized by x-ray diffraction (XRD) and transmission electron microscopy (TEM). The particle size ranged from 9 to 32 nm, depending on the growth conditions. At lower evaporation temperature and inert gas pressure, smaller particles with spherical shape showing less agglomeration are formed. Based on the experimental results and theoretical model of surface free energy and undercooling as a function of evaporation temperature and inert gas pressure, particle formation is analyzed. A simple operating map for nanoparticle synthesis is presented. The theoretical model is well supported by the experimental data.

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References

  1. C. Baker, A. Pradhan, L. Pakstis, J. Pochan Darrin, and S. Ismat Shah: Synthesis and antibacterial properties of silver nanoparticles. J. Nanosci. Nanotechnol. 5(2), 244 (2005).

    Article  CAS  Google Scholar 

  2. S. Zhang, R. Fu, D. Wu, W. Xu, Q. Ye, and Z. Chen: Preparation and characterization of antibacterial silver dispersed activated carbon aerogels. Carbon 42, 3209 (2004).

    Article  CAS  Google Scholar 

  3. G.J. Chi, S.W. Yao, J. Fan, W.G. Zhang, and H.Z. Wang: Antibacterial activity of anodized aluminum with deposited silver. Surf. Coat. Technol. 157, 162 (2002).

    Article  CAS  Google Scholar 

  4. U. Backman, J.K. Jokiniemi, A. Auvinen, and K.E.J. Lehtinen: The effect of boundary conditions on gas phase synthesized silver nanoparticles. J. Nanopart. Res. 4, 325 (2002).

    Article  CAS  Google Scholar 

  5. E. Matijevic: The world of fine particles. Chemtech. 21, 176 (1991).

    CAS  Google Scholar 

  6. M. Raffi, J.I. Akhter, and M.M. Hasan: Effect of annealing temperature on Ag nano-composite synthesized by sol-gel. Mater. Chem. Phys. 99, 405 (2006).

    Article  CAS  Google Scholar 

  7. C.C. Koch: The synthesis and structure of nanocrystalline materials produced by mechanical attrition: A review. Nanostruct. Mater. 2, 109 (1993) (Overview paper No. 2).

    Article  CAS  Google Scholar 

  8. R.L. Holtz and V. Provenzano: Enhanced micro hardness of copper–niobium nanocomposites. Nanostruct. Mater. 4, 241 (1994).

    Article  CAS  Google Scholar 

  9. C.G. Granqvist and R.A. Buhrman: Ultrafine metal particles. J. Appl. Phys. 47, 2200 (1976).

    Article  CAS  Google Scholar 

  10. R. Birringer, H. Gleiter, H.P. Klein, and P. Marquardt: Nanocrystalline materials, an approach to a novel solid structure with gas like disorder. Phys. Lett. A 102(8), 365 (1984).

    Article  Google Scholar 

  11. R.C. Flagan and M.M. Lunden: Particle structure control in nanoparticle synthesis from the vapor phase. Mater. Sci. Eng., A 204, 113 (1995).

    Article  Google Scholar 

  12. K.E.J. Lehtinen, U. Backman, J.K. Jokiniemi, and M. Kulmala: Three-body collisions as a particle formation mechanism in silver nanoparticle synthesis. J. Colloid Interface Sci. 274, 526 (2004).

    Article  CAS  Google Scholar 

  13. A. Simchi, R. Ahmadi, S.M.S. Reihani, and A. Mahdavi: Kinetics and mechanisms of nanoparticle formation and growth in vapor phase condensation process. Mater. Des. 28, 850 (2007).

    Article  CAS  Google Scholar 

  14. E.A. Owen and G.I. Williams: A low temperature x-ray camera. J. Sci. Instrum. 31, 49 (1954).

    Article  CAS  Google Scholar 

  15. B.D. Cullity: Elements of X-Ray Diffraction, 2nd ed. (Addison–Wesley, Reading, MA, 1978).

    Google Scholar 

  16. M. Turker: Effect of production parameters on the structure and morphology of Ag nanopowders produced by inert gas condensation. Mater. Sci. Eng., A 367, 74 (2004).

    Article  Google Scholar 

  17. O. Kubaschewski, C.B. Alcock, and P.J. Spencer: Materials Thermochemistry, 6th ed. (Pergamon Press, New York, 1993).

    Google Scholar 

  18. O. Subbotina, N. Kishkoparov, and I. Frishberg: Investigation technique for studying kinetics and mechanisms of growth of metal/metal alloy nanoparticles in the process of vapor phase condensation, in Proceedings of Nanocrystalline Materials, PM2001 Conference (Nice, France, 2001). p.387.

    Google Scholar 

  19. V. Haas, R. Birringer, and H. Gleiter: Preparation and characterization of compacts from nanostructured powder produced in an aerosol flow condenser. Mater. Sci. Eng., A 246, 86 (1998).

    Article  Google Scholar 

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Acknowledgment

The authors sincerely acknowledge partial financial support of Higher Education Commission, Government of Pakistan for this research work.

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Authors and Affiliations

  1. Department of Chemical and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad-, 45650, Pakistan

    M. Raffi & M. M. Hasan

  2. Department of Physics and Astronomy, University of Delaware, Newark, Delaware, 19716, Pakistan

    Abdul K. Rumaiz & S. Ismat Shah

  3. Department of Materials Science and Engineering, University of Delaware, Newark, Delaware, 19716, Pakistan

    S. Ismat Shah

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  1. M. Raffi
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  2. Abdul K. Rumaiz
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  3. M. M. Hasan
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  4. S. Ismat Shah
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Correspondence to S. Ismat Shah.

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Raffi, M., Rumaiz, A.K., Hasan, M.M. et al. Studies of the growth parameters for silver nanoparticle synthesis by inert gas condensation. Journal of Materials Research 22, 3378–3384 (2007). https://doi.org/10.1557/JMR.2007.0420

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  • DOI: https://doi.org/10.1557/JMR.2007.0420

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