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High refractive index films of polymer nanocomposites

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Abstract

Solutions of PbS particles and gelatin were used for the preparation of nanocomposites by a spin-coating process. This allows for the preparation of nanocomposite films with controlled thickness, e.g., between 40 nm and 2 μm for a film containing 45 wt.% PbS. Surface roughness and film thickness were investigated by surface profilometry and scanning electron microscopy (SEM). The refractive index at 632.8 nm can be expressed by a linear function of the volume fraction of PbS in the range of 0 to 55 vol. % PbS. In this range, the refractive index increases from 1.5 to 2.5 with increasing PbS ratio and belongs, therefore, to the highest refractive indices known for polymeric composite materials.

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Zimmennann, L., Weibel, M., Caseri, W. et al. High refractive index films of polymer nanocomposites. Journal of Materials Research 8, 1742–1748 (1993). https://doi.org/10.1557/JMR.1993.1742

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  • DOI: https://doi.org/10.1557/JMR.1993.1742

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