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Size-controllable synthesis of Fe3O4 nanoparticles through oxidation–precipitation method as heterogeneous Fenton catalyst

Published online by Cambridge University Press:  17 August 2016

Dong Wan
Affiliation:
School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
Wenbing Li*
Affiliation:
School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
Guanghua Wang
Affiliation:
School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
Xiaobi Wei
Affiliation:
School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
*
a) Address all correspondence to this author. e-mail: liwenbing@wust.edu.cn
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Abstract

The particle size of Fe3O4 nanoparticles is controlled using a simple oxidation–precipitation method without any surfactant. The structure, morphology and physical properties of the synthesized Fe3O4 NPs were characterized using x-ray diffraction, scanning electron microscopy, transmission electron microscopy, x-ray photoelectron spectroscopy, Brunauer–Emmett–Teller, and vibrating sample magnetometer. As-prepared magnetite samples exhibited spherical morphology with average diameters of 30, 70, 250, and 600 nm, respectively. Activity of the synthesized Fe3O4 NPs was evaluated for the Fenton-like reaction, using rhodamine B (RhB) as a model molecule. The results showed that catalytic activity increases with the reduced particle size. The significant higher catalytic activity of the fine Fe3O4 NPs mainly originated from the higher specific surface area, due to the increase in exposed active site number and adsorption capacity. The reusability of 30 nm Fe3O4 NPs was also investigated after three successive runs, in which the RhB degradation performances showed a slight difference with the first oxidation cycle. This investigation is of great significance for the promising application of the heterogeneous Fenton catalyst with enhanced activity in the oxidative degradation of organic pollutants.

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Articles
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Kim, K.H. and Ihm, S.K.: Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters: A review. J. Hazard. Mater. 186(1), 16 (2011).Google Scholar
Nidheesh, P.V.: Heterogeneous Fenton catalysts for the abatement of organic pollutants from aqueous solution: A review. RSC Adv. 5(51), 40552 (2015).Google Scholar
Matta, R., Hanna, K., and Chiron, S.: Fenton-like oxidation of 2,4,6-trinitrotoluene using different iron minerals. Sci. Total Environ. 385(1–3), 242 (2007).Google Scholar
Xu, L. and Wang, J.: A heterogeneous Fenton-like system with nanoparticulate zero-valent iron for removal of 4-chloro-3-methyl phenol. J. Hazard. Mater. 186(1), 256 (2011).Google Scholar
Chen, L., Deng, C., Wu, F., and Deng, N.: Decolorization of the azo dye Orange II in a montmorillonite/H2O2 system. Desalination 281, 306 (2011).Google Scholar
Gu, L., Zhu, N., Guo, H., Huang, S., Lou, Z., and Yuan, H.: Adsorption and Fenton-like degradation of naphthalene dye intermediate on sewage sludge derived porous carbon. J. Hazard. Mater. 246–247, 145 (2013).Google Scholar
Song, S., Yang, H., Rao, R., Liu, H., and Zhang, A.: High catalytic activity and selectivity for hydroxylation of benzene to phenol over multi-walled carbon nanotubes supported Fe3O4 catalyst. Appl. Catal., A 375(2), 265 (2010).Google Scholar
Ucoski, G.M., Nunes, F.S., DeFreitas-Silva, G., Idemori, Y.M., and Nakagaki, S.: Metalloporphyrins immobilized on silica-coated Fe3O4 nanoparticles: Magnetically recoverable catalysts for the oxidation of organic substrates. Appl. Catal., A 459, 121 (2013).Google Scholar
Gao, L., Zhuang, J., Nie, L., Zhang, J., Zhang, Y., Gu, N., Wang, T., Feng, J., Yang, D., Perrett, S., and Yan, X.: Intrinsic peroxidase-like activity of ferromagnetic nanoparticles. Nat. Nanotechnol. 2(9), 577 (2007).Google Scholar
Zhang, J., Zhuang, J., Gao, L., Zhang, Y., Gu, N., Feng, J., Yang, D., Zhu, J., and Yan, X.: Decomposing phenol by the hidden talent of ferromagnetic nanoparticles. Chemosphere 73(9), 1524 (2008).Google Scholar
Xue, X., Hanna, K., Abdelmoula, M., and Deng, N.: Adsorption and oxidation of PCP on the surface of magnetite: Kinetic experiments and spectroscopic investigations. Appl. Catal., B 89(3–4), 432 (2009).Google Scholar
Sun, S.P. and Lemley, A.T.: p-Nitrophenol degradation by a heterogeneous Fenton-like reaction on nano-magnetite: Process optimization, kinetics, and degradation pathways. J. Mol. Catal. A: Chem. 349(1–2), 71 (2011).Google Scholar
Xu, L. and Wang, J.: Fenton-like degradation of 2,4-dichlorophenol using Fe3O4 magnetic nanoparticles. Appl. Catal., B 123–124, 117 (2012).Google Scholar
Wang, N., Zhu, L., Wang, D., Wang, M., Lin, Z., and Tang, H.: Sono-assisted preparation of highly-efficient peroxidase-like Fe3O4 magnetic nanoparticles for catalytic removal of organic pollutants with H2O2 . Ultrason. Sonochem. 17(3), 526 (2010).Google Scholar
Liang, X., He, Z., Zhong, Y., Tan, W., He, H., Yuan, P., Zhu, J., and Zhang, J.: The effect of transition metal substitution on the catalytic activity of magnetite in heterogeneous Fenton reaction: In interfacial view. Colloids Surf., A 435, 28 (2013).Google Scholar
Peng, F.F., Zhang, Y., and Gu, N.: Size-dependent peroxidase-like catalytic activity of Fe3O4 nanoparticles. Chin. Chem. Lett. 19(6), 730 (2008).Google Scholar
Shen, Y.F., Tang, J., Nie, Z.H., Wang, Y.D., Ren, Y., and Zuo, L.: Tailoring size and structural distortion of Fe3O4 nanoparticles for the purification of contaminated water. Bioresour. Technol. 100(18), 4139 (2009).Google Scholar
Hou, L., Zhang, Q., Jérôme, F., Duprez, D., Zhang, H., and Royer, S.: Shape-controlled nanostructured magnetite-type materials as highly efficient Fenton catalysts. Appl. Catal., B 144, 739 (2014).Google Scholar
Zhang, G., Qie, F., Hou, J., Luo, S., Luo, L., Sun, X., and Tan, T.: One-pot solvothermal method to prepare functionalized Fe3O4 nanoparticles for bioseparation. J. Mater. Res. 27(7), 1006 (2012).Google Scholar
Asuha, S., Suyala, B., Siqintana, X., and Zhao, S.: Direct synthesis of Fe3O4 nanopowder by thermal decomposition of Fe-urea complex and its properties. J. Alloys Compd. 509(6), 2870 (2011).Google Scholar
Prakash, A., McCormick, A.V., and Zachariah, M.R.: Aero-sol−gel synthesis of nanoporous iron-oxide particles: a potential oxidizer for nanoenergetic materials. Chem. Mater. 16(8), 1466 (2004).Google Scholar
Petcharoen, K. and Sirivat, A.: Synthesis and characterization of magnetite nanoparticles via the chemical co-precipitation method. Mater. Sci. Eng., B 177(5), 421 (2012).Google Scholar
Li, L., Ding, J., and Xue, J.: A facile green approach for synthesizing monodisperse magnetite nanoparticles. J. Mater. Res. 25(5), 810 (2010).Google Scholar
Yan, A., Liu, X., Qiu, G., Wu, H., Yi, R., Zhang, N., and Xua, J.: Solvothermal synthesis and characterization of size-controlled Fe3O4 nanoparticles. J. Alloys Compd. 458(1–2), 487 (2008).Google Scholar
Meng, H., Zhang, Z., Zhao, F., Qiu, T., and Yang, J.: Orthogonal optimization design for preparation of Fe3O4 nanoparticles via chemical coprecipitation. Appl. Surf. Sci. 280, 679 (2013).Google Scholar
Zhang, Y., Shi, W., Feng, D., Ma, H., Liang, Y., and Zuo, J.: Application of rhodamine B thiolactone to fluorescence imaging of Hg2+ in Arabidopsis thaliana. Sens. Actuators, B 153(1), 261 (2011).Google Scholar
Chai, B., Zou, F., and Chen, W.: Facile synthesis of Ag3PO4/C3N4 composites with improved visible light photocatalytic activity. J. Mater. Res. 30(8), 1128 (2015).Google Scholar
Xue, X., Hanna, K., and Deng, N.: Fenton-like oxidation of Rhodamine B in the presence of two types of iron (II, III) oxide. J. Hazard. Mater. 166(1), 407 (2009).Google Scholar
Gan, P.P. and Li, S.F.Y.: Efficient removal of rhodamine B using a rice hull-based silica supported iron catalyst by Fenton-like process. Chem. Eng. J. 229, 351 (2013).Google Scholar
Wang, X., Pan, Y., Zhu, Z., and Wu, J.: Efficient degradation of rhodamine B using Fe-based metallic glass catalyst by Fenton-like process. Chemosphere 117, 638 (2014).Google Scholar
Liu, S., Lu, F., Xing, R., and Zhu, J.J.: Structural effects of Fe3O4 nanocrystals on peroxidase-like activity. Chem. - Eur. J. 17(2), 620 (2011).Google Scholar
Yu, W., Zhang, T., Zhang, J., Qiao, X., Yang, L., and Liu, Y.: The synthesis of octahedral nanoparticles of magnetite. Mater. Lett. 60(24), 2998 (2006).Google Scholar
Yang, S., He, H., Wu, D., Chen, D., Liang, X., Qin, Z., Fan, M., Zhu, J., and Yuan, P.: Decolorization of methylene blue by heterogeneous Fenton reaction using Fe3−x Ti x O4 (0 < x < 0.78) at neutral pH values. Appl. Catal., B 89(3–4), 527 (2009).Google Scholar
Tao, K., Dou, H., and Sun, K.: Interfacial coprecipitation to prepare magnetite nanoparticles: Concentration and temperature dependence. Colloids Surf., A 320(1–3), 115 (2008).Google Scholar
Goya, G.F., Berquó, T.S., Fonseca, F.C., and Morales, M.P.: Static and dynamic magnetic properties of spherical magnetite nanoparticles. J. Appl. Phys. 94(5), 3520 (2003).Google Scholar
Wan, D., Li, W., Wang, G., Chen, K., Lu, L., and Hu, Q.: Adsorption and heterogeneous degradation of rhodamine B on the surface of magnetic bentonite material. Appl. Surf. Sci. 349, 988 (2015).Google Scholar
Yamashita, T. and Hayes, P.: Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials. Appl. Surf. Sci. 254(8), 2441 (2008).Google Scholar
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