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Supercapacitance properties of porous carbon from chemical blending of phenolic resin and aliphatic dicarboxylic acids

Published online by Cambridge University Press:  24 May 2016

Xiaohong Xia ,
Xuefang Zhang ,
Shangqi Yi ,
Hui Chen  and
Hongbo Liu
Xiaohong Xia
Affiliation:
College of Materials Science and Engineering, Hunan University, Changsha 410082, People's Republic of China; and Hunan Province Key Laboratory for Spray Deposition Technology and Application, Hunan University, Changsha, Hunan, 410082, People's Republic of China
Xuefang Zhang
Affiliation:
College of Materials Science and Engineering, Hunan University, Changsha 410082, People's Republic of China
Shangqi Yi
Affiliation:
College of Materials Science and Engineering, Hunan University, Changsha 410082, People's Republic of China
Hui Chen
Affiliation:
College of Materials Science and Engineering, Hunan University, Changsha 410082, People's Republic of China
Hongbo Liu*
Affiliation:
College of Materials Science and Engineering, Hunan University, Changsha 410082, People's Republic of China; and Hunan Province Key Laboratory for Spray Deposition Technology and Application, Hunan University, Changsha, Hunan, 410082, People's Republic of China
*
a)Address all correspondence to this author. e-mail: xxh@hnu.edu.cn
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Abstract

We have reported the chemical blending carbonization method to obtain microporous carbon with high surface area for application as electrode materials in supercapacitors. Aliphatic dicarboxylic acids with different methylene numbers (n = 2, 4, 6, and 8) react with phenolic resin (PF) during curing process. Abundant micropores are created in the carbon matrix after the decomposition of grafted or blocked diacids at temperature higher than 400 °C. The specific surface area (SSA) of the carbonized blending system increases with the diacid chain length, but decreases after n > 4 of the chain length. The maximum SSA of the blending system is up to 605.9 m2/g, which increased approximately 68% compared to that of the neat carbonized PF. Electrochemical investigation indicates that the highest specific capacitances of the blending system reaches 175 F/g at a specific current of 0.1 A/g in 30 wt% KOH aqueous electrolyte. Furthermore, the capacitance maintenance achieves 82.8% as the current density enlarged 55 times.

Keywords

microporous materialsphenolic resinaliphatic dicarboxylic acidschemical blendingelectrochemical properties
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 12 , 28 June 2016 , pp. 1665 - 1673
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Copyright
Copyright © Materials Research Society 2016 

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