Microfossil (pollen and diatom) evidence is presented from sites in the Forth valley, south-central Scotland, where alternating organic and estuarine minerogenic deposits record the influence of the changing Holocene sea level. Radiocarbon dating confirms the age of the Main and Low Buried Beaches, and of the Main Postglacial Transgression, in different parts of the Forth valley. Radiocarbon dates on shells from beds in the carse sediment and a Mesolithic shell midden near Grangemouth relate to the falling sea level in the 4th and 5th millennia BP. Sea-level curves are constructed for the western and eastern Forth valley.

Collections from the Barr Group (late Llanvirn to early Caradoc) of the Girvan district are described and occurrences of all trilobites from both the Barr and Albany groups are listed and their frequencies recorded. The close relationships with North American faunas are emphasised, and three Girvan and North American species are considered synonymous. One new species is described, Bevanopsis phyllisae. Pandaspinapyga is considered a junior subjective synonym of Acanthoparypha. The possibility that Alwynulus may be an aberrant staurocephalid is discussed.

Growth stages of several genera are illustrated; some show unexpectedly large differences in size and morphology in comparison with North American silicified species at the same general stage of development.

Carboniferous sandstones from within the thermal aureoles of igneous intrusions in the Midland Valley of Scotland sometimes have a strong, black colour and are termed ‘black sandstones’. Tait (1926) concluded that the black sandstones are the products of the thermal metamorphism of petroliferous sandstones, a theory which is discussed here in the light of modern petrological and geochemical techniques.

The black colour of the sandstones is due to an amorphous, opaque bitumen which usually coats illitic clays, fills porosity and was mostly emplaced at a fairly late diagenetic stage. This solid bitumen has a low reflectance (c. 0·15% R0), no fluorescence under blue-light excitation, is insoluble in organic solvents, is isotopically heavy and has a very low H/C atomic ratio. These data, together with the field relationships of the black sandstones and igneous intrusions, suggest that the bitumen was formed by the thermal alteration of hydrocarbons, as described by Tait (1926), rather than by other possible mechanisms such as the deasphalting of an oil, or the generation of hydrocarbons from organic-rich rocks heated by igneous intrusions, followed by fractionation during migration. This conclusion suggests that by the time of emplacement of the quartz-dolerite intrusions, and some of the alkali-dolerite sills, there had been widespread generation and migration of hydrocarbons which possibly could have been preserved to the present day where not thermally altered.

The Eleonore Bay Supergroup (EBG) is a 16 km-thick shallow-water sequence of Neoproterozoic age that is preserved within the East Greenland Caledonides in several tracts, surrounded by crystalline gneisses and schistose supracrustal rocks. The apparent downward transition from non-metamorphic EBG into gneiss gave rise to the classic ‘stockwerke’ hypothesis, in which all the metamorphism was regarded as Caledonian, and differences in grade were ascribed to the ascent of a migmatite front to different levels within the orogen. Field and isotopic studies in the 1970s however revealed that the underlying gneisses and schists had undergone orogenic reworking in mid-Proterozoic time; the EBG–basement contact was then interpreted as an approximately bedding-parallel décollement with apparent lag geometry, that is with EBG cover rocks in its hangingwall.

Recent work in the northernmost EBG tract, at Ardencaple Fjord, has shed light on the problems posed by the basal relationships of the EBG, and together with regional structural and stratigraphic data leads to the following interpretation. There are two regionally important basement-cover interfaces within the East Greenland Caledonides. The earlier one is between Archaean/early Proterozoic gneisses and early Proterozoic supracrustal rocks, which were pervasively deformed in mid-Proterozoic time and form the basement to the Neoproterozoic Eleonore Bay cover sequence. This was deposited on a vast, continually subsiding shelf that is now preserved in East and NE Greenland and Svalbard, and contains Grenville detritus. EBG deposition was terminated by major extensional faulting of Vendian age; the succeeding Tillite Group is interpreted as a syn-rift sequence, presumably associated with the opening of Iapetus.

The EBG–basement contacts that are not late faults are inferred to be extensional shear zones of Vendian age. These were reactivated in compression during the Caledonian orogeny in the Silurian, with metamorphic and fabric convergence, which accounts for the apparent downward transition from sedimentary rocks through schists into gneisses. Caledonian shortening was not large; inversion of the Vendian grabens was incomplete, so that the marginal shear zones retained their lag geometry and large tracts of low grade Eleonore Bay sediments are preserved at the present erosion level, surrounded by Proterozoic basement rocks, within the Caledonian belt of East Greenland.

A brief history of research into the unusual laminated and spherulitic East Kirkton Limestone (Brigantian, Viséan) is given. It documents the paucity of fossil finds until 1984, when S. P. Wood discovered a previously unsuspected terrestrial biota. Some early finds, such as stromatolites, have since been overlooked, while others were misinterpreted, e.g. a ‘fish-bone’ collected before 1870 proves to be amphibian. A formal lithostratigraphic description is given of the three beds that comprise the c. 15 m sequence in East Kirkton Quarry: the East Kirkton Limestone, overlain by Little Cliff Shale and Geikie Tuff, the latter two being here formally named. Lithological descriptions and a unit-by-unit distribution of major elements of the biota are provided for a measured section comprising 88 units. This is based on bed-by-bed excavations carried out 1985-92, supplemented by nine boreholes. Two 3 m-thick massive limestones lenses are recorded from the quarry and a probable third was proved in a borehole. Brief reports are given on the ‘stromatolites’ (by M. R. Walter), bivalve molluscs (R. M. C. Eagar and R. B. Wilson), ostracods (J. Pollard) and gypsum pseudomorphs.

Mass balance equations are derived which link the ratios Ts/ (suspended load/dissolved load from chemical weathering) and Tb/Ts (bed load/suspended load), with any two geochemical components present in the source rock and the alluvial system. If the dissolved load is unknown the ratios can be estimated from the relatively insoluble silica and alumina. The ratio Ts/, which for large river basins depends on climate and relief, can thus potentially be determined from ancient alluvial sequences.

The equations help define the source composition of a group of 13 modern rivers for which Ts, and alluvial geochemistry are known. These rivers together drain 27% of the continental surface. For a source area with the average continental sandstone to shale ratio of 0·6 the observed average value of Ts/ is obtained when limestone, sandstone and shale are present in the proportions 6·7:21·6:35·7. The figure of 64% sediment in the source area is very similar to the 66% determined by Blatt and Jones (1975) from geological maps of the continents. The equations also show that average bed load transport rate into these 13 basins is about 27% of total transport, and into the Amazon basin about 37%. Bed load transport rates out of the basins, into the sea, are relatively very small.

A sporomorph assemblage recovered from the Sandy's Creek Beds, which constitute a diminutive fault bounded inlier on the west coast of the Midland Valley of Scotland, is described. Four species of trilete spore and the genus Fustisispora, a monospecific cryptospore genus, are proposed as new. The sporomorph assemblage is attributed an early Devonian, late–early to early–late Lochkovian age, and is interpreted as accumulating in a continental environment. The Sandy's Creek Beds are correlated herein with the upper part of the Arbuthnott Group which crops out in the north-east of the Midland Valley. Comparison with other sporomorph assemblages of similar age indicates that minor regional variation exists. It is suggested that this is related to small-scale regional variation in the composition of vegetation.

The southern Bathgate Hills, in the eastern part of the Midland Valley basin of Scotland, were the site of a volcanic rise during late Dinantian to early Silesian times and a sequence of basaltic lavas and tuffs up to 600 m thick accumulated. The volcanic pile interrupted the regional sedimentary deposition, which involved a cyclical sequence of marine limestones and mudstones followed by estuarine, lagoonal and deltaic clastic deposits. During the Brigantian Stage of the Dinantian, freshwater terrestrial environments developed locally on the volcanic rise between eruptive phases, but later in the Brigantian the rise was transgressed by marine limestones. Intermittent basaltic eruptions continued into the Amsbergian Stage of the Silesian, accompanied by intrusion of high-level alkaline doleritic sills and associated with strata-bound Zn—Pb mineralisation. Folding later in the Silesian was followed by the intrusion of a suite of quartz-dolerite sills and dykes. These latter were commonly intruded along penecontemporaneous E—W trending faults. The intrusion of the quartz-dolerites may have resulted in remobilisation of earlier strata-bound mineralisation into epigenetic veins.

Magnetic and resistivity geophysical surveys conducted across the only known exposure of the East Kirkton Limestone have produced new information upon its extent. This is important to determine because of its unique faunal assemblage and possible hot spring deposition, suggesting a potential for precious metal mineralisation. Magnetic anomalies are attributed to basalts within the Bathgate Hills Volcanic Formation. Modelling of the magnetic data demonstrates a general dip to the west of about 25°, and the presence of significant local faulting. Modelling of vertical electrical sounding data shows the East Kirkton sequence (the limestone and associated beds) to be a low resistivity layer within the more highly resistive volcanic sequence. The East Kirkton sequence is seen to deepen to the west, and also to the north probably by faulting. Therefore the present exposure is the only near surface occurrence of the East Kirkton Limestone locally, but within the area of the survey no lateral limits to the formation are observed.

In the Southern Uplands of Scotland, the youngest greywackes along the SE margin of the Northern Belt are shown to be of Ashgill age. Mudstones interbedded with the dominantly quartzose greywackes of the Shinnel Formation have yielded Dicellograptus anceps, indicating the anceps Biozone. In addition, the newly-defined mafic-rich Glenlee Formation, lying to the SE of the Shinnel Formation in the New Galloway-Moniaive area, has yielded fossils of the pacificus Subzone, the upper subzone of the anceps Biozone. Since the oldest greywackes of the Central Belt, separated from the Northern Belt by the Orlock Bridge Fault, are now confirmed as of basal Silurian acuminatus Biozone age, the stratigraphical break across the Orlock Bridge Fault is greatly reduced, lending support to the ‘single terrane’ model for the Southern Uplands.

The Mandala drainage basin lies in the central part of the West African craton immediately to the south of the regional watershed. There has been frequent kimberlite dyke intrusion in the basin. The kimberlites range in grade from apparently barren to having a high diamond content. The presence of other undiscovered kimberlites can be inferred from the distribution, chemistry and abundance of kimberlite satellite minerals and variations in diamond size and character. Secondary diamond deposits are widespread with the main concentrations in the present and former Mandala valley bottoms. Tributaries have lower diamond contents. There are systematic variations in the alluvial diamond characteristics which can be explained in terms of diamond sources as well as transport of the diamonds away from those sources. The occurrence of the secondary diamond deposits is explained by the form and distribution of the primary sources, the nature of the drainage network and the long-term evolution of the drainage basin. Since the Pliocene or Early Pleistocene the Mandala has been rejuvenated with incision of the main channel by up to 26 m. This incision has led to flushing of the tributaries and storage of sediment, including diamonds, in the principal channel.

The Lower Ordovician (Oeland Series) type species of Lamanskya, L. splendens Moberg & Segerberg 1906, was described originally as an articulate brachiopod, but it is here redescribed and referred to the lingulid Family Elkaniidae. L. splendens ranges from the late Tremadoc to the early Arenig in Baltoscandia (Norway, Sweden, Estonia, and the St Petersburg district of Russia). Aulonotreta kuraganica Andreeva 1972 from the Lower Ordovician of the Ural Mountains is also redescribed and referred to Lamanskya. The genus Dictyobolus Williams & Curry 1985, from the Lower Ordovician of Ireland, is a junior synomym of Lamanskya. All species of the genus are strongly biconvex, and have a well-developed ornamentation of elongate lenticular pits. The problematic Genus Volborthia von Moller 1870 is also considered tentatively to belong within the Elkaniidae.

Volcanogenic sediments form a significant part of the East Kirkton Limestone, with thin tuff units occurring at several levels and pyroclastic fragments being an important constituent of the coarser clastic limestone units.

The tuffs have been extensively altered during diagenesis but recognisable pseudomorphs after olivine and plagioclase phenocrysts confirm the basaltic nature of the volcanism. The considerable lateral variations in thickness of the tuff horizons in conjunction with the poorly sorted and lithologically heterogeneous nature of the tuffs indicate an epiclastic origin for the volcanogenic sediments. Well-rounded volcanic rock fragments—products of erosion—occur with angular fragments within the tuffs. Blocky tuffs in the lower part of the formation contain charred wood fragments, rip-up clasts of limestone and disarticulated amphibian bones. Graded bedding at several horizons and the presence of ostracods within some tuffs confirms subaqueous deposition.

The findings are consistent with the usual, dominantly epiclastic products of basaltic volcanism, in an equatorial, continental, humid environment, with assorted debris being washed from the flanks of a volcano into a shallow lake.

The Ordovician and Silurian successions between Falahill and Galashiels encompass six flysch-dominated formations: the Upper Ordovician Portpatrick and Shinnel Formations representing the Leadhills Group, the Llandovery Mindork, Garheugh, and Buckholm Formations together comprising the Gala Group, and a formation indeterminate of age within the Hawick Group. Southward ensialic andesitic volcanic arc and northward low- to medium-grade sialic sources contributed sediment, whilst ophiolitic and subduction-related sources made minor contributions. Deposition took place firstly, in a SE-migrating back-arc basin bordering the northerly source, the Laurentian continent. Subsequent NW-directed underthrusting led to formation out of the back-arc basin of an imbricate thrust stack which migrated southeastwards. Ultimately a foreland successor basin formed ahead of the rising thrust stack.

Flysch units are typically associated with linear outcrops of Moffat Shales which are the loci of major steep SE-translating reverse faults, two of which participate in a late-stage sinistral strike–slip duplex with large-scale imbrication. The faults divide the succession into a sequence of tectonostratigraphic blocks, successively younger to the SE. At least six of the ten blocks customarily recognised in the Southern Uplands, Blocks 3–8, are represented, some of which coincide with single or complete formations.

In the early Carboniferous, the portion of continental crust that now constitutes Scotland lay within the hinterland of a large continent that extended westwards to what is now the western parts of North America, eastwards to what is now the Urals and northwards towards what is now Arctic Canada, Greenland, Scandinavia and Russia. Open ocean probably lay at between 600 and 1000 km to the south. Whereas mountainous terrane lay to the north of the Highland Boundary fault, the Scottish Midland Valley, like the Northumberland Trough further south, was a region of low relief subject to periodic marine incursions.

A period of block faulting and concomitant basaltic volcanism commenced at the beginning of the Carboniferous at c. 350 Ma. This had manifestations in various regions of the British Isles from the south-west of England to the west of Ireland and as far north as the Midland Valley (Francis 1978, 1991; Upton 1982; Cameron and Stephenson 1985).

The East Kirkton Limestone is typically a carbonate/organic laminite characterised at many levels by abundant radial-fibrous calcite (RFC) spherules and by less common larger stromatolite-like accretions of laminated botryoidal RFC. The spherules are mostly c. 1 mm in diameter and have cyanophyte and chlorophyte inclusions. Some spherules enclose parallel bundles of complete cyanophyte fibres and probably grew within a living cyanophyte mat. The botryoidal accretions were commonly seeded upon wood and other exposed organic remains such as bone, and they completely enclose twigs and branches where these were held above the sediment surface. Botryoidal accretions commonly contain the remains of a benthos of cyanophytes, chlorophytes and ostracods.

Both types of calcite have carbon and oxygen stable isotope values similar to those of known fresh-water precipitates. Their stable isotope and trace element geochemistries are consistent with precipitation on the floor of a tropical fresh-water lake within a volcanic setting, but removed from the influence of any hot-spring activity. Spherules and botroids are mineralogically closely similar and, whilst precipitation may have been biogenically mediated, they are regarded as passive lake floor cements.

The carbonate laminae are dominated by rhombohedral calcite. Many of these laminae may have originated as calcite suspensoids which settled to the lake floor during relatively brief precipitation events, blanketing the normally richly organic substrate, smothering the cyanophyte mats, and leading to the preservation of individual organic laminae. Crystals later became enlarged and intergrown within the sediment, but this occurred early and prior to significant compaction, because detail of fragile and degradable organic constituents is commonly preserved. The likely source of the carbonate is through leaching of the local basic volcanic terrain. The precipitation of two types of calcite implies regular fluctuations in the chemistry of the lake waters, or in the factors controlling precipitation, which may have been a biogenic and/or seasonal effect.