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Roll-to-Roll Coating by Liquid Flame Spray Nanoparticle Deposition

Published online by Cambridge University Press:  28 May 2015

Jyrki M. Mäkelä ,
Janne Haapanen ,
Mikko Aromaa ,
Hannu Teisala ,
Mikko Tuominen ,
Milena Stepien ,
Jarkko J. Saarinen ,
Martti Toivakka  and
Jurkka Kuusipalo
Jyrki M. Mäkelä
Affiliation:
Aerosol Physics Laboratory Tampere University of Technology, P.O.Box 589, FI-33101 Tampere, Finland.
Janne Haapanen
Affiliation:
Aerosol Physics Laboratory Tampere University of Technology, P.O.Box 589, FI-33101 Tampere, Finland.
Mikko Aromaa
Affiliation:
Aerosol Physics Laboratory Tampere University of Technology, P.O.Box 589, FI-33101 Tampere, Finland.
Hannu Teisala
Affiliation:
Paper Converting and Packaging Technology, Tampere University of Technology, P.O.Box 589, FI-33101 Tampere, Finland.
Mikko Tuominen
Affiliation:
Paper Converting and Packaging Technology, Tampere University of Technology, P.O.Box 589, FI-33101 Tampere, Finland.
Milena Stepien
Affiliation:
Laboratory of Paper Coating and Converting and Center of Functional Materials, Åbo Akademi University, Porthaninkatu 3, FI-20500 Turku, Finland.
Jarkko J. Saarinen
Affiliation:
Laboratory of Paper Coating and Converting and Center of Functional Materials, Åbo Akademi University, Porthaninkatu 3, FI-20500 Turku, Finland.
Martti Toivakka
Affiliation:
Laboratory of Paper Coating and Converting and Center of Functional Materials, Åbo Akademi University, Porthaninkatu 3, FI-20500 Turku, Finland.
Jurkka Kuusipalo
Affiliation:
Paper Converting and Packaging Technology, Tampere University of Technology, P.O.Box 589, FI-33101 Tampere, Finland.
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Abstract

Nanostructured coatings have been prepared on a flexible, moving paperboard using deposition of ca. 10-50-nm-sized titanium dioxide and silicon dioxide nanoparticles generated by a liquid flame spray process, directly above the paperboard, to achieve improved functional properties for the material. With moderately high production rate (∼ g/min), the method is applicable for thin aerosol coating of large area surfaces. LFS-made nanocoating can be synthesized e.g. on paper, board or polymer film in roll-to-roll process. The degree of particle agglomeration is governed by both physicochemical properties of the particle material and residence time in aerosol phase prior to deposition. By adjusting the speed of the substrate, even heat sensitive materials can be coated. In this study, nanoparticles were deposited directly on a moving paperboard with line speeds 50-300 m/min. Functional properties of the nanocoating can be varied by changing nanoparticle material; e.g. TiO2 and SiO2 are used for changing the surface wetting properties. If the liquid precursors are dissolved in one solution, synthesis of multi component nanoparticle coatings is possible in a one phase process. Here, we present analysis of the properties of LFS-fabricated nanocoatings on paperboard. The thermophoretic flux of nanoparticles is estimated to be very high from the hot flame onto the cold substrate. A highly hydrophobic coating was obtained by a mass loading in the order of 50–100 mg/m2 of titanium dioxide on the paperboard.

Keywords

nanostructurecoatingflame synthesis
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1747: Symposium HH – Flame and High-Temperature Synthesis of Functional Nanomaterials—Fundamentals and Applications , 2015 , mrsf14-1747-hh03-03
Copyright
Copyright © Materials Research Society 2015 

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