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Thio-oxynitride phosphate glass electrolytes prepared by mechanical milling

Published online by Cambridge University Press:  21 May 2015

Nerea Mascaraque Open the ORCID record for Nerea Mascaraque [Opens in a new window] ,
José Luis G. Fierro ,
Francisco Muñoz ,
Alicia Durán ,
Yusuke Ito ,
Yoshiaki Hibi ,
Ryo Harada ,
Atsutaka Kato ,
Akitoshi Hayashi  and
Masahiro Tatsumisago
Nerea Mascaraque*
Affiliation:
Glasses Department, Instituto de Cerámica y Vidrio (CSIC), Cantoblanco, Madrid 28049, Spain
José Luis G. Fierro
Affiliation:
Group of Sustainable Energy and Chemistry, Instituto de Catálisis y Petroquímica (CSIC), Cantoblanco, Madrid 28049, Spain
Francisco Muñoz
Affiliation:
Glasses Department, Instituto de Cerámica y Vidrio (CSIC), Cantoblanco, Madrid 28049, Spain
Alicia Durán
Affiliation:
Glasses Department, Instituto de Cerámica y Vidrio (CSIC), Cantoblanco, Madrid 28049, Spain
Yusuke Ito
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
Yoshiaki Hibi
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
Ryo Harada
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
Atsutaka Kato
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
Akitoshi Hayashi
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
Masahiro Tatsumisago
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
*
a)Address all correspondence to this author. e-mail: mascaraque@icv.csic.es
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Abstract

Lithium thio-phosphorus oxynitride glasses, LiPOSN, have been prepared by mechanical milling process from the mixture of Li2S and LiPON glass. The anionic substitution of oxygen by sulphur and nitrogen in the phosphate glass structure has been confirmed by 1D 31P solid state nuclear magnetic resonance and x-ray photoelectron spectroscopy. The study of thermal and electrical properties reveals a decrease in the glass transition temperature, likely due to the depolymerization of glass network by the decrease of bridging oxygens and sulphurs, along with a sharp increase in the ionic conductivity when lithium sulphide is incorporated into the oxynitride glasses. The improvement of chemical durability by the introduction of nitrogen, together with the increase in ionic conductivity up to values closed to the value of commercial LiPON thin film electrolyte, suggests that these LiPOSN glasses could be good candidates as solid electrolytes for lithium microbatteries.

Keywords

solid electrolytesthio-phosphorus oxynitride materialsLiPOSN structure
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 19: Focus Issue: Nitrides and Oxynitride Materials , 14 October 2015 , pp. 2940 - 2948
Copyright
Copyright © Materials Research Society 2015 

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References

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