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Investigation of flowing liquid zinc erosion and corrosion properties of the Fe–B alloy at various times

Published online by Cambridge University Press:  13 February 2015

Guangzhu Liu
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Shengqiang Ma*
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Jiandong Xing
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Hanguang Fu
Affiliation:
Research Institute of Advanced Materials Processing Technology, School of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, People's Republic of China
Yuan Gao
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Yaping Bai
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
Yong Wang
Affiliation:
State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi Province 710049, People's Republic of China
*
a)Address all correspondence to this author. e-mail: sqma@mail.xjtu.edu.cn
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Abstract

The erosion–corrosion properties and interface microstructure of a Fe–B alloy that contains 3.5 wt% B in flowing liquid zinc have been investigated by electron backscattered diffraction, x-ray diffraction, and scanning electron microscopy to clarify the flowing effect of liquid zinc on erosion performance using a rotating-disk technique. The Fe–B alloy erodes at a low and steady rate in flowing liquid zinc. Flowing liquid zinc can accelerate the iron and zinc mass transfer to form Fe–Zn compounds and promote the removal of loose FeZn13. Much residual corrosion-resistant Fe2B and some erosion products coexist at the erosion interface because of the chemical and micromechanical effects that are created by flowing liquid zinc. The failure of the Fe2B corrosion-resistant skeleton in flowing liquid zinc occurs because of the loss of supporting matrix and also the formation and spread of microcracks during erosion.

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Articles
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Park, J.H., Park, G.H., Paik, D.J., Huh, Y., and Hong, M.H.: Influence of aluminum on the formation behavior of Zn-Al-Fe intermetallic particles in a zinc bath. Metall. Mater. Trans. A 43A, 195 (2012).Google Scholar
Marder, A.R.: The metallurgy of zinc-coated steel. Prog. Mater. Sci. 45, 191 (2000).Google Scholar
Xu, J., Bright, M.A., Liu, X.B., and Barbero, E.: Liquid metal corrosion of 316L stainless steel, 410 stainless steel, and 1015 carbon steel in a molten zinc bath. Metall. Mater. Trans. A 38, 2727 (2007).Google Scholar
Brunnock, M.S., Jones, R.D., Jenkins, G.A., and Llewellyn, D.T.: Interactions between liquid zinc and bath hardware materials in continuous galvanizing lines. Ironmaking Steelmaking 23, 171 (1996).Google Scholar
Liu, X.B., Barbero, E., Xu, J., Burris, M., Chang, K.M., and Sikka, V.: Liquid metal corrosion of 316L, Fe3Al, and Fe-Cr-Si in molten Zn-Al baths. Metall. Mater. Trans. A 36A, 2049 (2005).Google Scholar
Brunnock, M.S., Jones, R.D., Jenkins, G.A., and Llewellyn, D.T.: Investigation of the interactions between liquid zinc and stainless steels for use in continuous galvanizing hardware. Zinc-Based Steel Coating Systems: Production and Performance (TMS Symposium), 1998; p. 51.Google Scholar
Tani, K., Tomita, T., Kobayashi, Y., Takatani, Y., and Harada, Y.: Durability of sprayed WC/Co coatings in Al- added zinc bath. ISIJ Int. 34, 822 (1994).Google Scholar
Seong, B.G., Hwang, S.Y., Kim, M.C., and Kim, K.Y.: Reaction of WC/Co coating with molten zinc in a zinc pot of a continuous galvanizing line. Surf. Coat. Technol. 138, 101 (2001).Google Scholar
Brunnock, M.S., Jones, R.D., Jenkins, G.A., and Llewellyn, D.T.: Supermeniscus interactions between molten zinc and bath hardware materials in galvanizing. Ironmaking Steelmaking 24, 40 (1997).Google Scholar
Wang, W.J., Lin, J.P., Wang, Y.L., and Chen, G.L.: The corrosion of intermetallic alloys in liquid zinc. J. Alloys Compd. 428, 237 (2007).Google Scholar
Dong, Y.C., Yan, D.R., He, J.N., Zhang, J.X., and Li, X.Z.: Degradation behaviour of ZrO2-Ni/Al gradient coatings in molten Zn. Surf. Coat. Technol. 201, 2455 (2006).Google Scholar
Tsipas, D.N. and Perez-Perez, C.: A boronizing treatment for low-carbon steels. J. Mater. Sci. Lett. 1, 298 (1982).Google Scholar
Rus, J., Leal, C.L.D., and Tsipas, D.N.: Boronizing of 304 steel. J. Mater. Sci. Lett. 4, 558 (1985).Google Scholar
Stergioudis, G.: Formation of boride layers on steel substrates. Cryst. Res. Technol. 41, 1002 (2006).Google Scholar
Palombarini, G. and Carbucicchio, M.: High boron phases on borided iron and iron alloys. J. Mater. Sci. Lett. 4, 170 (1985).Google Scholar
Carbucicchio, M., Palombarini, G., and Sambogna, G.: Surface iron-boron reaction products on low-alloy substrates. Hyperfine Interact. 41, 617 (1988).Google Scholar
Tsipas, D.N. and Rus, J.: Boronizing of alloy steels. J. Mater. Sci. Lett. 6, 118 (1987).Google Scholar
Tsipas, D.N., Triantafyllidis, G.K., Kiplagat, J.K., and Psillaki, P.: Degradation behaviour of boronized carbon and high alloy steels in molten aluminium and zinc. Mater. Lett. 37, 128 (1998).Google Scholar
Ma, S.Q., Xing, J.D., Fu, H.G., Yi, D.W., Zhi, X.H., and Li, Y.F.: Effects of boron concentration on the corrosion resistance of Fe-B alloys immersed in 460 °C molten zinc bath. Surf. Coat. Technol. 204, 2208 (2010).Google Scholar
Cao, X.M., Ma, R.N., Wu, J.J., Wen, M., Fan, Y.Z., and Du, A.: Influences of Si on corrosion of Fe-B alloy in liquid zinc. Corros. Eng., Sci. Technol. 37, 1840 (2003).Google Scholar
Wang, W.J., Lin, J.P., Wang, Y.L., and Chen, G.L.: The corrosion of Fe3Al alloy in liquid zinc. Corros. Sci. 49, 1340 (2007).Google Scholar
Tang, N., Li, Y.P., Kurosu, S., Koizumi, Y., Matsumoto, H., and Chiba, A.: Interfacial reactions of solid Co and solid Fe with liquid Al. Corros. Sci. 60, 32 (2012).Google Scholar
Ma, S.Q., Xing, J.D., Yi, D.W., Fu, H.G., and Liu, G.F.: Microstructure and corrosion behavior of cast Fe-B alloys dipped into liquid zinc bath. Mater. Charact. 61, 866 (2010).Google Scholar
Short, M.P., Ballinger, R.G., and Hänninen, H.E.: Corrosion resistance of alloys F91 and Fe-12Cr-2Si in lead-bismuth eutectic up to 715 °C. J. Nucl. Mater. 434, 259 (2013).Google Scholar
Gulsoy, G., Was, G.S., Pawel, S.J., and Busby, J.T.: Degradation modes of austenitic and ferritic-martensitic stainless steels in He-CO-CO2 and liquid sodium environments of equivalent oxygen and carbon chemical potentials. J. Nucl. Mater. 441, 633 (2013).Google Scholar
Verma, A.R.B. and van Ooij, W.J.: High-temperature batch hot-dip galvanizing. Part 1. General description of coatings formed at 560 °C. Surf. Coat. Technol. 89, 132 (1997).Google Scholar
Verma, A.R.B. and van Ooij, W.J.: High-temperature batch hot-dip galvanizing. Part 2. Comparison of coatings formed in the temperature range 520-555 °C. Surf. Coat. Technol. 89, 143 (1997).Google Scholar
Arafin, M.A. and Szpunar, J.A.: A new understanding of intergranular stress corrosion cracking resistance of pipeline steel through grain boundary character and crystallographic texture studies. Corros. Sci. 51, 119 (2009).Google Scholar
Gertsman, V.Y. and Bruemmer, S.M.: Study of grain boundary character along intergranular stress corrosion crack paths in austenitic alloys. Acta Mater. 49, 1589 (2001).Google Scholar
Shimada, M., Kokawa, H., Wang, Z.J., Sato, Y.S., and Karibe, I.: Optimization of grain boundary character distribution for intergranular corrosion resistant 304 stainless steel by twin-induced grain boundary engineering. Acta Mater. 50, 2331 (2002).Google Scholar
Tsurekawa, S., Nakamichi, S., and Watanabe, T.: Correlation of grain boundary connectivity with grain boundary character distribution in austenitic stainless steel. Acta Mater. 54, 3617 (2006).Google Scholar
Guérin, M., Andrieu, E., Odemer, G., Alexis, J., and Blanc, C.: Effect of varying conditions of exposure to an aggressive medium on the corrosion behavior of the 2050 Al-Cu-Li alloy. Corros. Sci. 85, 455 (2014).Google Scholar
Lapeire, L., Martinez Lombardia, E., Verbeken, K., De Graeve, I., Kestens, L.A.I., and Terryn, H.: Combined EBSD and AFM study of the corrosion behaviour of ETP-Cu. Mater. Sci. Forum 702, 673 (2012).Google Scholar
Jones, C.P., Scott, T.B., Petherbridge, J.R., and Glascott, J.: A surface science study of the initial stages of hydrogen corrosion on uranium metal and the role played by grain microstructure. Solid State Ionics 231, 81 (2013).Google Scholar
Campos, I., Palomar, M., Amador, A., Ganem, R., and Martinez, J.: Evaluation of the corrosion resistance of iron boride coatings obtained by paste boriding process. Surf. Coat. Technol. 201, 2438 (2006).Google Scholar
Giorgl, M.L., Durighello, P., and Nicolle, R.: Dissolution kinetics of iron in liquid zinc. J. Mater. Sci. 39, 5803 (2004).Google Scholar
Dybkov, V.I.: Reaction Diffusion and Solid State Chemical Kinetics, 1st ed. (The IPMS Publications, Kyiv, Ukraine, 2002); pp. 215217.Google Scholar
Assael, M.J., Armyra, I.J., Brillo, J., Stankus, S.V., Wu, J.T., and Wakeham, W.A.: Reference data for the density and viscosity of liquid cadmium, cobalt, gallium, indium, mercury, silicon, thallium, and zinc. J. Phys. Chem. Ref. Data 4, 033101 (2012).Google Scholar
Celerier, F.B. and Barbier, F.: Investigation of models to predict the corrosion of steels in flowing liquid lead alloys. J. Nucl. Mater. 289, 227 (2001).Google Scholar
Niinomi, M., Ueda, Y., and Sano, M.: Dissolution of ferrous alloys into molten aluminium. Trans. Jpn. Inst. Met. 23, 780 (1982).CrossRefGoogle Scholar
Cussler, E.L.: Diffusion mass transfer in fluid systems, 3rd ed. (Cambridge University Press, New York, America, 2007); p. 293.Google Scholar