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Trace phase detection and strain characterization from serial X-ray free-electron laser crystallography of a Pr0.5Ca0.5MnO3 powder

Published online by Cambridge University Press:  17 November 2014

Kenneth R. Beyerlein*
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany
Christian Jooss
Affiliation:
Institute of Materials Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37085Göttingen, Germany
Anton Barty
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany
Richard Bean
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany
Sébastien Boutet
Affiliation:
Linac Coherent Light Source (LCLS), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California94025
Sarnjeet S. Dhesi
Affiliation:
Diamond Light Source, OX11 0DE Oxfordshire, United Kingdom
R. Bruce Doak
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
Michael Först
Affiliation:
Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761Hamburg, Germany
Lorenzo Galli
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany Department of Physics, University of Hamburg, Jungiusstr. 6, 20355Hamburg, Germany
Richard A. Kirian
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany
Joseph Kozak
Affiliation:
Swanson School of Engineering, University of Pittsburgh, 3700 O'Hara Street, Pittsburgh, Pennsylvania15261
Michael Lang
Affiliation:
Institute of Materials Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37085Göttingen, Germany
Roman Mankowsky
Affiliation:
Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761Hamburg, Germany
Marc Messerschmidt
Affiliation:
Linac Coherent Light Source (LCLS), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California94025
John C. H. Spence
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
Dingjie Wang
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
Uwe Weierstall
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
Thomas A. White
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany
Garth J. Williams
Affiliation:
Linac Coherent Light Source (LCLS), SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California94025
Oleksandr Yefanov
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany
Nadia A. Zatsepin
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
Andrea Cavalleri
Affiliation:
Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761Hamburg, Germany Department of Physics, University of Hamburg, Jungiusstr. 6, 20355Hamburg, Germany
Henry N. Chapman
Affiliation:
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, 22607 Hamburg, Germany Department of Physics, University of Hamburg, Jungiusstr. 6, 20355Hamburg, Germany Centre for Ultrafast Imaging, Luruper Chaussee 149, 22607 Hamburg, Germany
*
a)Author to whom correspondence should be addressed. Electronic mail: kenneth.beyerlein@cfel.de

Abstract

We report on the analysis of virtual powder-diffraction patterns from serial femtosecond crystallography (SFX) data collected at an X-ray free-electron laser. Different approaches to binning and normalizing these patterns are discussed with respect to the microstructural characteristics which each highlights. Analysis of SFX data from a powder of Pr0.5Ca0.5MnO3 in this way finds evidence of other trace phases in its microstructure which was not detectable in a standard powder-diffraction measurement. Furthermore, a comparison between two virtual powder pattern integration strategies is shown to yield different diffraction peak broadening, indicating sensitivity to different types of microstrain. This paper is a first step in developing new data analysis methods for microstructure characterization from serial crystallography data.

Type
Technical Articles
Copyright
Copyright © International Centre for Diffraction Data 2014 

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