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Laser-deposited CoCrMo alloy: Microstructure, wear, and electrochemical properties

Published online by Cambridge University Press:  22 July 2014

Kedar M. Mantrala*
Affiliation:
Department of Mechanical Engineering, Vasireddy Venkatadri Institute of Technology, Guntur 522508, India
Mitun Das
Affiliation:
Bioceramics & Coating Division, CSIR-Central Glass and Ceramic Research Institute (CGCRI), Kolkata 700032, India
Vamsi K. Balla*
Affiliation:
Bioceramics & Coating Division, CSIR-Central Glass and Ceramic Research Institute (CGCRI), Kolkata 700032, India
Ch. Srinivasa Rao
Affiliation:
Department of Mechanical Engineering, Andhra University College of Engineering, Visakhapatnam 530003, India
V.V.S. Kesava Rao
Affiliation:
Department of Mechanical Engineering, Andhra University College of Engineering, Visakhapatnam 530003, India
*
a)Address all correspondence to these authors. e-mail: vamsiballa@cgcri.res.in
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Abstract

CoCrMo alloy was deposited on a metallic substrate using laser engineered net shaping (LENS™) – a laser-based additive manufacturing technique. Several samples with five layers of deposit were fabricated at different combinations of laser power, powder feed rate, and scan velocity to study their influence using L4 Orthogonal array. The deposits were evaluated for their microstructure, hardness, wear resistance, and electrochemical performance. Grey relational grade analysis and analysis of variance were applied to identify optimum process parameters. The x-ray diffraction and microstructural analysis of the deposits showed uniform and fine microstructural features. Our experimental results revealed that the coatings fabricated using high laser power (350 W), low powder feed rate (5 g/min), and high scan velocity (20 mm/s) provide the highest hardness (446 ± 2.87 Hv) and wear resistance (1.80 ± 0.0007 mm3/Nm). However, the corrosion resistance was observed to be high for the deposits fabricated using low laser power (200 W), low powder feed rate (5 g/min), and low scan velocity (10 mm/s).

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Amstutz, H.C. and Grigoris, P.: Metal on metal bearings in hip arthroplasty. Clin. Orthop. Relat. Res. 329S, 11 (1996).CrossRefGoogle Scholar
Liao, Y., Pourzal, R., Stemmer, P., Wimmer, M.A., Jacobs, J.J., Fischer, A., and Marks, L.D.: New insights into hard phases of CoCrMo metal-on-metal hip replacements. J. Mech. Behav. Biomed. Mater. 12, 39 (2012).Google Scholar
Giacchi, J.V., Morando, C.N., Fornaro, O., and Palacio, H.A.: Microstructural characterization of as-cast biocompatible Co–Cr–Mo alloys. Mater. Charact. 62, 53 (2011).CrossRefGoogle Scholar
Julian, L.C. and Munoz, A.: Influence of microstructure of HC CoCrMo biomedical alloys on the corrosion and wear behavior in simulated body fluids. Tribol. Int. 44, 318 (2011).Google Scholar
Gil, R.A. and Muñoz, A.I.: Influence of the sliding velocity and the applied potential on the corrosion and wear behavior of HC CoCrMo biomedical alloy in simulated body fluids. J. Mech. Behav. Biomed. Mater. 4, 2090 (2011).Google Scholar
España, F.A., Balla, V.K., Bose, S., and Bandyopadhyay, A.: Design and fabrication of CoCrMo based novel structures for load bearing implants using laser engineered net shaping. Mater. Sci. Eng., C 30(1), 50 (2010).Google Scholar
Ram, G.D.J., Esplin, C.K., and Stucker, B.E.: Microstructure and wear properties of LENS deposited medical grade CoCrMo. J. Mater. Sci.: Mater. Med. 19, 2105 (2008).Google Scholar
Krishna, B.V., Xue, W., Bose, S., and Bandyopadhyay, A.: Functionally graded Co-Cr-Mo coating on Ti-6Al-4V alloy structures. Acta Biomater. 4(3), 697 (2008).CrossRefGoogle Scholar
Dittrick, S., Balla, V.K., Davies, N.M., Bose, S., and Bandyopadhyay, A.: In vitro wear rate and Co ion release of compositionally and structurally graded CoCrMo-Ti6Al4V structures. Mater. Sci. Eng., C 31(4), 809 (2011).Google Scholar
Das, M., Balla, V.K., Sampath Kumar, T.S., and Manna, I.: Fabrication of biomedical implants using laser engineered net shaping (LENSTM). Trans. Indian Ceram. Soc. 72(3), 169 (2013).CrossRefGoogle Scholar
Mazumder, J., Schifferer, A., and Choi, J.: Direct materials deposition: Designed macro and microstructure. Mater. Res. Innovations 3(3), 118 (1999).Google Scholar
Bontha, S., Klingbeil, N.W., Kobryn, P.A., and Fraser, H.L.: Thermal process maps for predicting solidification microstructure in laser fabrication of thin-wall structures. J. Mater. Process. Technol. 178, 135 (2006).CrossRefGoogle Scholar
Hofmeister, W., Griffith, M., Ensz, M., and Smugeresky, J.: Solidification in direct metal deposition by LENS processing. JOM 53(9), 30 (2001).Google Scholar
Gäumann, M., Henry, S., Cleton, F., Wagniere, J.D., and Kurz, W.: Epitaxial laser metal forming: Analysis of microstructure formation. Mater. Sci. Eng., A 271, 232 (1999).CrossRefGoogle Scholar
Kurz, W., Bezencon, C., and Gäumann, M.: Columnar to equiaxed transition in solidification processing. Sci. Technol. Adv. Mater. 2, 185 (2001).Google Scholar
España, F.A., Balla, V.K., and Bandyopadhyay, A.: Laser processing of bulk Al-12Si alloy: Influence of microstructure on thermal properties. Philos. Mag. 91(4), 574 (2011).CrossRefGoogle Scholar
Das, M., Balla, V.K., Basu, D., Manna, I., Sampath Kumar, T.S., and Bandyopadhyay, A.: Laser processing of in-situ synthesized TiB-TiN reinforced Ti6Al4V alloy composite coatings. Scr. Mater. 66(8), 578 (2012).CrossRefGoogle Scholar
Balla, V.K., Bandyopadhyay, P.P., Bose, S., and Bandyopadhyay, A.: Compositionally graded yttria-stabilized zirconia coating on stainless steel using laser engineered net shaping (LENS). Scr. Mater. 57, 861 (2007).Google Scholar
Ortega-Saenz, J.A., Hernandez-Rodriguez, M.A.L., Ventura-Sobrevilla, V., Michalczewski, R., Smolik, J., and Szczerek, M.: Tribological and corrosion testing of surface engineered surgical grade CoCrMo alloy. Wear 271, 2125 (2011).CrossRefGoogle Scholar
Roy, S. and Sahoo, P.: Potentiodynamic polarization behavior of electroless Ni-P-W coatings. ISRN Corros. 2012, 914867 (2012).CrossRefGoogle Scholar