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Preparation of indole surface molecularly imprinted polymer by atom transfer radical emulsion polymerization and its adsorption performance

Published online by Cambridge University Press:  24 September 2013

Yang Wenming ,
Cao Yang ,
Xu Xiaoling ,
Zhou Zhiping ,
Liu Lukuan  and
Xu Wanzhen
Yang Wenming*
Affiliation:
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
Cao Yang*
Affiliation:
School of the Environment, Jiangsu University, Zhenjiang 212013, China
Xu Xiaoling
Affiliation:
School of the Environment, Jiangsu University, Zhenjiang 212013, China
Zhou Zhiping*
Affiliation:
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
Liu Lukuan
Affiliation:
School of the Environment, Jiangsu University, Zhenjiang 212013, China
Xu Wanzhen*
Affiliation:
School of the Environment, Jiangsu University, Zhenjiang 212013, China
*
a)Address all correspondence to these authors. e-mail: zhouzp@ujs.edu.cn
b)e-mail: xwz09@ujs.edu.cn
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Abstract

The indole molecularly imprinted polymer (indole-MIP) was synthesized by atom transfer radical emulsion polymerization (ATREP). The novel adsorbent was used to adsorb indole from fuel oil. The indole-MIP had a high selectivity to indole, and the mass transfer limitations were overcome. The property and morphology of indole-MIP were described by a series of characterization methods. A great specific area and more pores of indole-MIP were shown. The static adsorption experiments display that equilibrium adsorption capacity of indole-MIP was 34.488 mg/g. The adsorption process was spontaneous by thermodynamic analysis, and a dense mass of indole was adsorbed onto indole-MIP at a proper low temperature (298 K). Pseudo-second-order kinetic model was more fitted with experimental data. Both Langmuir and Freundlich isotherm models were obeyed by adsorption isotherm test. The selective and competitive performances of indole-MIP were favorable, and the regeneration capacity was appreciable.

Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 19 , 14 October 2013 , pp. 2666 - 2676
Copyright
Copyright © Materials Research Society 2013 

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References

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