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Synchrotron X-ray studies of metal-organic framework M2(2,5-dihydroxyterephthalate), M = (Mn, Co, Ni, Zn) (MOF74)

Published online by Cambridge University Press:  30 November 2012

W. Wong-Ng ,
J. A. Kaduk ,
H. Wu  and
M. Suchomel
W. Wong-Ng*
Affiliation:
National Institute of Standards and Technology, Gaithersburg, Maryland 20899
J. A. Kaduk
Affiliation:
Illinois Institute of Technology, Chicago, Illinois 60616
H. Wu
Affiliation:
National Institute of Standards and Technology, Gaithersburg, Maryland 20899
M. Suchomel
Affiliation:
Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439-4856
*
a)Author to whom correspondence should be addressed. Electronic mail: winnie.wong-ng@nist.gov
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Abstract

M2(dhtp)·nH2O (M = Mn, Co, Ni, Zn; dhtp = 2,5-dihydroxyterephthalate), known as MOF74, is a family of excellent sorbent materials for CO2 that contains coordinatively unsaturated metal sites and a honeycomb-like structure featuring a broad one-dimensional channel. This paper describes the structural feature and provides reference X-ray powder diffraction patterns of these four isostructural compounds. The structures were determined using synchrotron diffraction data obtained at beam line 11-BM at the Advanced Photon Source (APS) in the Argonne National Laboratory. The samples were confirmed to be hexagonal R 3 (No. 148). From M = Mn, Co, Ni, to Zn, the lattice parameter a of MOF74 ranges from 26.131 73(4) Å to 26.5738(2) Å, c from 6.651 97(5) to 6.808 83(8) Å, and V ranges from 3948.08 Å3 to 4163.99 Å3, respectively. The four reference X-ray powder diffraction patterns have been submitted for inclusion in the Powder Diffraction File (PDF).

Keywords

Metal-organic frameworkMOF74M2(2,5-dihydroxyterephthalate)·nH2O(M = Mn, Co, Ni, Zn)Synchrotron X-rayHigh resolution diffraction patterns
Type
Technical Articles
Information
Powder Diffraction , Volume 27 , Issue 4 , December 2012 , pp. 256 - 262
Copyright
Copyright © International Centre for Diffraction Data 2012

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