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Diamond-graphite hybrids and the nature of amorphous carbon and diamond-like carbon

Published online by Cambridge University Press:  03 March 2011

Rahul Sen ,
R. Sumathy  and
C.N.R. Rao
Rahul Sen
Affiliation:
CSIR Centre of Excellence in Chemistry and Materials Research Centre, Indian Institute of Science, Bangalore 560 012, India
R. Sumathy
Affiliation:
CSIR Centre of Excellence in Chemistry and Materials Research Centre, Indian Institute of Science, Bangalore 560 012, India
C.N.R. Rao*
Affiliation:
CSIR Centre of Excellence in Chemistry and Materials Research Centre, Indian Institute of Science, Bangalore 560 012, India
*
a)Author to whom all correspondence should be addressed.
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Abstract

The nature of amorphous carbon has been explored by molecular mechanics by examining the structures of species such as C84Hx and C150Hx, wherein the percentage of sp3 carbons is progressively increased in a graphitic network. The nature of diamond-like carbon has been similarly investigated by examining the structures of C84Hx and C102Hx where the percentage of sp2 carbons is varied in an sp3 network. The dependence of the average coordination number as well as the sp3/sp2 atom ratio on the atom fraction of hydrogen has been investigated in light of the random covalent network model.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 10 , October 1995 , pp. 2531 - 2535
Copyright
Copyright © Materials Research Society 1995

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References

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