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Role of Atomic Size and Valence in Bonding and Diffusion at Metal Surfaces

Published online by Cambridge University Press:  25 February 2011

Peter J. Feibelman
Peter J. Feibelman*
Affiliation:
Surface and Interface Sciences, Department Sandia National Laboratories Albuquerque, NM 87185
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Abstract

First-principles calculations and corresponding experimental results underline the importance of basic chemical concepts in understanding bonding and diffusion of atoms at and on metal surfaces. Examples discussed include the outward relaxation of clean Be(0001), the separation energies of metal-adatom dimers, concerted substitutional self-diffusion on fcc(001) and (110) surfaces, and adsorption and diffusion barrier sites for adatoms near steps.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 280: Symposium B – Evolution of Surface and Thin Film Microstructure , 1992 , 31
Copyright
Copyright © Materials Research Society 1993

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References

REFERENCES

1. For a review of the Local Density Functional method see The Theory of the Electron Gas, edited by Lundqvist, S. and March, N. H. (Plenum Press, New York, 1983).Google Scholar
2. Andersen, O. K., Phys. Rev. B12, 3060(1975);CrossRefGoogle Scholar
Hamann, D. R., Phys. Rev. Lett. 42, 662(1979);CrossRefGoogle Scholar
Mattheiss, L. F and Hamann, D. R., Phys. Rev. B33, 823(1986).CrossRefGoogle Scholar
3. Williams, A. R., Feibelman, P. J. and Lang, N. D., Phys. Rev B26, 5433(1982);Google Scholar
Feibelman, P. J., Phys. Rev B35, 2626(1987);Google Scholar
Feibelman, P. J., Phys. Rev B39, 4866(1989).Google Scholar
4. Feibelman, P. J., Phys. Rev B46, 2532(1992).Google Scholar
5. Feibelman, P. J., Phys. Rev. Lett. 58, 2766(1987).Google Scholar
6. Feibelman, P. J., Phys. Rev. Lett. 65, 729(1990).Google Scholar
7. Kellogg, G. L. and Feibelman, P. J., Phys. Rev. Lett. 64, 3143(1990);CrossRefGoogle Scholar
Chen, C. and Tsong, T. T., Phys. Rev. Lett. 64, 3147(1990).CrossRefGoogle Scholar
8. Feibelman, P. J., Phys. Rev. Lett. 69, 1568(1992).CrossRefGoogle Scholar
9. Davis, H. L., Hannon, J. B., Ray, K. B. and Plummer, E. W., Phys. Rev. Lett. 68, 2632(1992).Google Scholar
10. See Ref. 5 for a lengthy list of references.Google Scholar
11. Pauling, L., The Nature of the Chemical Bond (Cornell Univ. Press, Ithaca, NY, 1960), 3rd ed. Google Scholar