MRS Proceedings

Articles

Searching for New Thermoelectrics in Chemically and Structurally Complex Bismuth Chalcogenides

1997 MRS Spring Meeting.

Duck Young Chunga1, Tim Hogana2, Jon Schindlera2, Lykourgos Iordanidisa1, Paul Brazisa2, Carl R. Kannewurfa2, Baoxing Chena3, Ctirad Uhera3 and Mercouri G. Kanatzidisa1

a1 Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI 48824.

a2 Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, IL 60208

a3 Department of Physics, University of Michigan, Ann Arbor, MI 48109

Abstract

A solid state chemistry synthetic approach towards identifying new materials with potentially superior thermoelectric properties is presented. Materials with complex compositions and structures also have complex electronic structures which may give rise to high thermoelectric powers and at the same time possess low thermal conductivities. The structures and thermoelectric properties of several new promising compounds with K-Bi-Se, K-Bi-S, Ba-Bi- Te, Cs-Bi-Te, and Rb-Bi-Te are reported.

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