Journal of Materials Research

Articles

An investigation of carbon nanotubes obtained from the decomposition of methane over reduced Mg1−xMxAl2O4 spinel catalysts

A. Govindaraja1, E. Flahauta2, Ch. Laurenta2, A. Peigneya2, A. Rousseta2 and C. N. R. Raoa3

a1 CSIR Centre of Excellence in Chemistry, Indian Institute of Science, Bangalore 560012, India

a2 Laboratoire de Chimie des Matériaux Inorganiques, ESA CNRS 5070, Université Paul-Sabatier, 31062 Toulouse cedex 4, France

a3 CSIR Centre of Excellence in Chemistry, Indian Institute of Science, Bangalore 560012, India and Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560064, India

Abstract

Carbon nanotubes produced by the treatment of Mg1−xMxAl2O4 (M = Fe, Co, or Ni; x = 0.1, 0.2, 0.3, or 0.4) spinels with an H2–CH4 mixture at 1070 °C have been investigated systematically. The grains of the oxide-metal composite particles are uniformly covered by a weblike network of carbon nanotube bundles, several tens of micrometers long, made up of single-wall nanotubes with a diameter close to 4 nm. Only the smallest metal particles (<5 nm) are involved in the formation of the nanotubes. A macroscopic characterization method involving surface area measurements and chemical analysis has been developed in order to compare the different nanotube specimens. An increase in the transition metal content of the catalyst yields more carbon nanotubes (up to a metal content of 10.0 wt% or x = 0.3), but causes a decrease in carbon quality. The best compromise is to use 6.7 wt% of metal (x = 0.2) in the catalyst. Co gives superior results with respect to both the quantity and quality of the nanotubes. In the case of Fe, the quality is notably hampered by the formation of Fe3C particles.

(Received June 09 1998)

(Accepted January 06 1999)

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