MRS Proceedings

Table of Contents - Volume  1211  - Symposium R – Advanced Nanostructured Solar Cells  

Editors : A.J. Frank, N-G. Park, T. Miyasaka, L. Peter, S. Dai

Articles

Recent Advances of Dye-Sensitized Solar Cells and Integrated Modules at SHARP

2009 MRS Fall Meeting.

Naoki Koidea1, Ryohsuke Yamanakaa2 and Hiroyuki Katayamaa3

a1 koide.naoki@sharp.co.jp, Sharp Corporation, New Technology Development Center, Nara, Japan

a2 yamanaka.ryohsuke@sharp.co.jp, Sharp Corporation, New Technology Development Center, Nara, Japan

a3 Katayama.hiroyuki@sharp.co.jp, Sharp Corporation, New Technology Development Center, Nara, Japan

Abstract

An equivalent circuit for DSCs was studied using electrochemical impedance spectroscopy measurement, and the improvements of conversion efficiency of DSCs for not only single cells but also integrated modules were investigated. Further improvement of cell characteristics of DSCs was also investigated from the view point of modified TiO2 films and series-internal resistance design. The series-internal resistance elements were found to correlate positively with the sheet resistance of the transparent conducting oxide and the thickness of the electrolyte layer and negatively with the roughness factor of the platinum counter-electrode. The short circuit current density (Jsc) of the DSCs was effectively improved by use of a high-haze TiO2 film. In addition, the analysis of TiO2/dye interface by scanning probe microscopy and transient absorption spectroscopy were also useful for the study. As a result, the maximum single cell conversion efficiency of over 11% was obtained. Furthermore, an integrated DSC module composed of many rectangular cells connected in series was fabricated and the efficiency was increased to 8.4% (confirmed by AIST) by realizing high active area and high uniformity.

(Received November 19 2009)

(Accepted August 06 2010)

Key Words

  • photovoltaic;
  • nanostructure;
  • organic
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