Hostname: page-component-8448b6f56d-c47g7 Total loading time: 0 Render date: 2024-04-19T22:39:08.316Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrodeposited Cu2Sb as anode material for 3-dimensional Li-ion microbatteries

Published online by Cambridge University Press:  31 January 2011

Emilie Perre ,
Pierre Louis Taberna ,
Driss Mazouzi ,
Philippe Poizot ,
Torbjörn Gustafsson ,
Kristina Edström  and
Patrice Simon
Emilie Perre*
Affiliation:
Université de Toulouse, CIRIMAT-UMR CNRS 5085, 31062 Toulouse Cedex 4, France; Department of Materials Chemistry, The A˚ngström Advanced Battery Centre, Uppsala University, SE 751 21 Uppsala, Sweden; and Alistore European Research Institute, 80039 Amiens Cedex, France
Pierre Louis Taberna
Affiliation:
Université de Toulouse, CIRIMAT-UMR CNRS 5085, 31062 Toulouse Cedex 4, France; and Alistore European Research Institute, 80039 Amiens Cedex, France
Philippe Poizot
Affiliation:
Alistore European Research Institute, 80039 Amiens Cedex, France; and LRCS-UMR 6007, Université de Picardie Jules Verne, 80039 Amiens, France
Kristina Edström
Affiliation:
Department of Materials Chemistry, The A˚ngström Advanced Battery Centre, Uppsala University, SE 751 21 Uppsala, Sweden; and Alistore European Research Institute, 80039 Amiens Cedex, France
Patrice Simon
Affiliation:
Université de Toulouse, CIRIMAT-UMR CNRS 5085, 31062 Toulouse Cedex 4, France; and Alistore European Research Institute, 80039 Amiens Cedex, France
*
a)Address all correspondence to this author. e-mail: perre@chimie.ups-tlse.fr
Get access

Abstract

An increasing demand on high energy and power systems has arisen not only with the development of electric vehicle (EV), hybrid electric vehicle (HEV), telecom, and mobile technologies, but also for specific applications such as powering of microelectronic systems. To power those microdevices, an extra variable is added to the equation: a limited footprint area. Three-dimensional (3D) microbatteries are a solution to combine high-density energy and power. In this work, we present the formation of Cu2Sb onto three-dimensionally architectured arrays of Cu current collectors. Sb electrodeposition conditions and annealing post treatment are discussed in light of their influence on the morphology and battery performances. An increase of cycling stability was observed when Sb was fully alloyed with the Cu current collector. A subsequent separator layer was added to the 3D electrode when optimized. Equivalent capacity values are measured for at least 20 cycles. Work is currently devoted to the identification of the causes of capacity fading.

Keywords

LiEnergy storageMicrostructure
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 8: Materials for Electrical Energy Storage , August 2010 , pp. 1485 - 1491
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Long, J.W., Dunn, B., Rolison, D.R., White, H.S.Three-dimensional battery architectures. Chem. Rev. 104, 4463 (2004)Google Scholar
2.Min, H-S., Park, B.Y., Taherabadi, L., Wang, C., Yeh, Y., Zaouk, R., Madou, M.J., Dunn, B.Fabrication and properties of a carbon/polypyrrole three-dimensional microbattery. J. Power Sources 178, 795 (2008)CrossRefGoogle Scholar
3.Golodnitsky, D., Yufit, V., Nathan, M., Shechtman, I., Ripenbein, T., Strauss, E., Menkin, S., Peled, E.Advanced materials for the 3d microbattery. J. Power Sources 153, 281 (2006)Google Scholar
4.Taberna, P.L., Mitra, S., Poizot, P., Simon, P., Tarascon, J.M.High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications. Nat. Mater. 5, 567 (2006)Google Scholar
5.Nesper, R.Structure and chemical bonding in zintl-phases containing lithium. Prog. Solid State Chem. 20, 1 (1990)CrossRefGoogle Scholar
6.Beaulieu, L.Y., Eberman, K.W., Turner, R.L., Krause, L.J., Dahn, J.R.Colossal reversible volume changes in lithium alloys. Electrochem. Solid-State Lett. 4, A137 (2001)Google Scholar
7.Besenhard, J.O., Yang, J., Winter, M.Will advanced lithium-alloy anodes have a chance in lithium-ion batteries≟ J. Power Sources 68, 87 (1997)Google Scholar
8.Arico, A.S., Bruce, P., Scrosati, B., Tarascon, J.M., Van Schalkwijk, W.Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater. 4, 366 (2005)CrossRefGoogle ScholarPubMed
9.Thackeray, M.M., Vaughey, J.T., Johnson, C.S., Kropf, A.J., Benedek, R., Fransson, L.M.L., Edstrom, K.Structural considerations of intermetallic electrodes for lithium batteries. J. Power Sources 113, 124 (2003)Google Scholar
10.Kepler, K.D., Vaughey, J.T., Thackeray, M.M.LixCu6Sn5 (0 < x < 13): An intermetallic insertion electrode for rechargeable lithium batteries. Electrochem. Solid-State Lett. 2, 307 (1999)Google Scholar
11.Bryngelsson, H., Eskhult, J., Nyholm, L., Edström, K.Thin films of Cu2Sb and Cu9Sb2 as anode materials in Li-ion batteries. Electrochim. Acta 53, 7226 (2008)Google Scholar
12.Nathan, M., Golodnitsky, D., Yufit, V., Strauss, E., Ripenbein, T., Shechtman, I., Menkin, S., Peled, E.Three-dimensional thin-film Li-ion microbatteries for autonomous mems. J. Microelectromech. Syst. 14, 879 (2005)CrossRefGoogle Scholar
13.Song, J.Y., Wang, Y.Y., Wan, C.C.Review of gel-type polymer electrolytes for lithium-ion batteries. J. Power Sources 77, 183 (1999)Google Scholar
14.Fransson, L.M.L., Vaughey, J.T., Benedek, R., Edstrom, K., Thomas, J.O., Thackeray, M.M.Phase transitions in lithiated Cu2Sb anodes for lithium batteries: An in situ x-ray diffraction study. Electrochem. Commun. 3, 317 (2001)Google Scholar
15.Morcrette, M., Larcher, D., Tarascon, J.M., Edstrom, K., Vaughey, J.T., Thackeray, M.M.Influence of electrode microstructure on the reactivity of Cu2Sb with lithium. Electrochim. Acta 52, 5339 (2007)CrossRefGoogle Scholar
16.Matsuno, S., Noji, M., Kashiwagi, T., Nakayama, M., Wakihar, M.Construction of the ternary phase diagram for the Li–Cu–Sb system as the anode material for a lithium ion battery. J. Phys. Chem. C 111, 7548 (2007)CrossRefGoogle Scholar