a1 Department of Geotechnical Engineering and Geosciences, School of Civil Engineering, Technical University of Catalonia (UPC), C. Jordi Girona 1-3, 08034 Barcelona, Spain
a2 Institute of Environmental Assessment and Water Research, Spanish National Research Council (IDAEA-CSIC), C. Jordi Girona 18, 08034 Barcelona, Spain
Dissolution of carbon dioxide (CO2) injected into saline aquifers causes an unstable high-density diffusive front. Understanding how instability fingers develop has received much attention because they accelerate dissolution trapping, which favours long-term sequestration. The time for the onset of convection as the dominant transport mechanism has been traditionally studied by neglecting dispersion and treating the CO2–brine interface as a prescribed concentration boundary by analogy to a thermal convection problem. This work explores the effect of these simplifications. Results show that accounting for the CO2 mass flux across the prescribed concentration boundary has little effect on the onset of convection. However, accounting for dispersion causes a reduction of up to two orders of magnitude on the onset time. This implies that CO2 dissolution can be accelerated by activating dispersion as a transport mechanism, which can be achieved adopting a fluctuating injection regime.
(Received May 05 2009)
(Revised August 01 2009)
(Accepted August 03 2009)
(Online publication October 19 2009)