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Scapolite compositional change in a metamorphic gradient and its bearing on the identification of meta-evaporite sequences

Published online by Cambridge University Press:  01 May 2009

T. A. P. Kwak
Affiliation:
Department of Geology, La Trobe University, Bundoora, Victoria, Australia

Summary

Scapolite occurs in the NE Mt Lofty area of South Australia in rocks of bulk compositions as diverse as sulphide-rich veins, meta dolerite, scapolite (pelitic) schists, calc-silicate rocks and impure marbles. Scapolites analysed from all these rocks show with increasing grade a linear to near-linear change in composition from Me50 and Me66. Some scatter around these values is attributed to local perturbations of fCl/fCo2 in the fluid phase during metamorphism. Sulphur values as SO3 are below the 0.02 level even when scapolite occurs in contact with sulphides in a vein in a small copper mine; here, however, an interpreted FeO value of 2.58 weight % was recorded. The values in this study are comparable with those of Heitanen (1967), and are believed to be representative of products of normal metamorphic fluids evolved from non-evaporitic metamorphic rocks under a greenschist–amphibolite facies gradient; they can thus be used as a standard in assessing the possible significance of meta-evaporites in other areas.

Type
Articles
Copyright
Copyright © Cambridge University Press 1977

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References

Brauns, R. 1917. Neue skapolith fuhrende Auswurflinge aus dem Laacher Seegebiet. Neues Jb. Miner. Geol. pp. 944.Google Scholar
Chappell, B. W. & White, A. J. R. 1968. The X-ray spectrographic determination of sulphur co-ordination in scapolite. Am. Miner. 53, 1735–8.Google Scholar
Edwards, A. E. & Baker, G. 1954. Scapolitization in the Cloncurry District of North-Western Queensland. J. geol. Soc. Aust. 1, 131.CrossRefGoogle Scholar
Evans, B. W., Shaw, D. M. & Haughton, D. R. 1969. Scapolite stroichiometry. Contrib. Miner. Petrol. 24,293305.CrossRefGoogle Scholar
Goldsmith, J. R. 1976. Scapolites, granulites and volatiles in the lower crust. Bull. geol. Soc. Am. 87, 161–82.0.CO;2>CrossRefGoogle Scholar
Heitanen, A. 1967. Scapolite in the Belt Series, St Joe—Clearwater Region. Spec. Pap. Geol. Soc. Am. 86.Google Scholar
Lovering, J. F. & White, A. J. R. 1969. Granulitic and eclogitic inclusions from basic pipes at Delegate, Australia. Contr. Miner. Petrol. 21.CrossRefGoogle Scholar
Mason, P. K., Frost, M. T. & Read, S. J. B. 1969. Computer programs for calculating corrections in quantitative X-ray micro-analysis. Rep. No. 2, Div. of Inorganic and Metallic Structure, National Physical Laboratory, U.K.Google Scholar
Newton, R. C. & Goldsmith, J. R. 1975. Stability of the scapolite meionite (3 CaAl2Si2O2. CaCO3) at high pressure and storage of CO2 in the deep crust. Contr. Miner. Petrol. 49, 4962.CrossRefGoogle Scholar
Offler, R. & Fleming, P. D. 1968. A synthesis of folding and metamorphism in the Mount Lofty Ranges, South Australia. J. geol. Soc. Aust. 15 (2yes), 245–66.CrossRefGoogle Scholar
Orville, P. M. 1974. Stability of scapolite in the system Ab—An—NaCl—CaCO at 4 kb and 750 °C. Contr. Miner. Petrol 43.Google Scholar
Ramsay, C. R. & Davidson, L. R. 1969. The Origin of Scapolite in the Regionally Metamorphosed Rocks, Mary Kathleen, Queensland, Australia. Contr. Miner. Petrol. 25, 4151.CrossRefGoogle Scholar
Roedder, E. 1965. Liquid CO2 inclusions in olivine-bearing nodules and phenocrysts and basalts. Am. Miner. 50, 1746–81Google Scholar
Serdyuchenko, D. P. 1975. Some Precambrian scapolite-bearing rocks evolved from evaporites. Lithos 8,17.CrossRefGoogle Scholar
Shaw, D. M. 1960. The geochemistry of scapolite. I: Previous work and general mineralogy. II: Trace elements, petrology and general geochemistry. J. Petrol. 1, 218–85.CrossRefGoogle Scholar
White, A. J. R. 1959. Scapolite-bearing marbles and calc-silicates from Tungkillo and Milendella, South Australia. Geol. Mag. 96, 285306.CrossRefGoogle Scholar
Winchell, A. N. 1924. The properties of scapolite. Am. Miner. 9, 108–32.Google Scholar