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Nanotribological properties of few layer graphene surfaces, prepared by bottom-up and top-down methods, in ambient air and liquid environments

Published online by Cambridge University Press:  15 March 2016

Konstantinos A. Sierros ,
Sai Suvineeth Ramayanam  and
Charter D. Stinespring
Konstantinos A. Sierros*
Affiliation:
Department of Mechanical and Aerospace Engineering, West Virginia University, Morgantown, West Virginia 26506, USA
Sai Suvineeth Ramayanam
Affiliation:
Department of Mechanical and Aerospace Engineering, West Virginia University, Morgantown, West Virginia 26506, USA
Charter D. Stinespring
Affiliation:
Department of Chemical Engineering, West Virginia University, Morgantown, West Virginia 26506, USA
*
a)Address all correspondence to this author. e-mail: kostas.sierros@mail.wvu.edu
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Abstract

The role of bottom-up and top-down synthesis methods on the nanotribological response of few layer graphene (FLG) in air and various liquid environments is reported. Oxidized FLG adhesion against Si increases by a factor of 2 as compared to non-oxidized samples. Also, it is reported that the FLG center-to-edge adhesion typically exhibits a decreasing tendency. In air, a highly lubricious nanotribological response (0.03–0.04) of both bottom-up and top-down prepared samples is measured. The frictional behavior of bottom-up synthesized FLG in different liquid environments is found to depend on the absence or presence of viscous aggregates in the respective liquid. A Stribeck-like behavior is suggested for viscous synthetic lubricants, such as silicone, present as the third body in the FLG/Si tip system. Such nanoscale behavior, indicating transitions in different lubrication regimes, may be particularly important for the further understanding of liquid–graphene interfaces in novel tribological and device applications.

Keywords

tribologysurface chemistrylubricant
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 13: Focus Issue: Advances and Challenges in Carbon-based Tribomaterials , 14 July 2016 , pp. 1924 - 1931
Copyright
Copyright © Materials Research Society 2016 

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